Ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1H-pyrazole-5-carboxyl­ate

The title compound, [Fe(C(5)H(5))(C(17)H(16)N(3)O(2))], crystallizes with an essentially eclipsed conformation of the cyclo­penta­dienyl (Cp) rings. The unsubstituted ring is disordered over two positions with the major component being present 90 (1)% of the time. The substituted Cp ring, the pyrazo...

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Autores principales: Guzei, Ilia A., Spencer, Lara C., Munyaneza, Apollinaire, Darkwa, James
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254307/
https://www.ncbi.nlm.nih.gov/pubmed/22259337
http://dx.doi.org/10.1107/S160053681105238X
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author Guzei, Ilia A.
Spencer, Lara C.
Munyaneza, Apollinaire
Darkwa, James
author_facet Guzei, Ilia A.
Spencer, Lara C.
Munyaneza, Apollinaire
Darkwa, James
author_sort Guzei, Ilia A.
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(17)H(16)N(3)O(2))], crystallizes with an essentially eclipsed conformation of the cyclo­penta­dienyl (Cp) rings. The unsubstituted ring is disordered over two positions with the major component being present 90 (1)% of the time. The substituted Cp ring, the pyrazole ring and three atoms of the eth­oxy­carbonyl group form a conjugated π-system. These 13 atoms are coplanar within 0.09 Å.
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spelling pubmed-32543072012-01-18 Ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1H-pyrazole-5-carboxyl­ate Guzei, Ilia A. Spencer, Lara C. Munyaneza, Apollinaire Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(17)H(16)N(3)O(2))], crystallizes with an essentially eclipsed conformation of the cyclo­penta­dienyl (Cp) rings. The unsubstituted ring is disordered over two positions with the major component being present 90 (1)% of the time. The substituted Cp ring, the pyrazole ring and three atoms of the eth­oxy­carbonyl group form a conjugated π-system. These 13 atoms are coplanar within 0.09 Å. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254307/ /pubmed/22259337 http://dx.doi.org/10.1107/S160053681105238X Text en © Guzei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guzei, Ilia A.
Spencer, Lara C.
Munyaneza, Apollinaire
Darkwa, James
Ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1H-pyrazole-5-carboxyl­ate
title Ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1H-pyrazole-5-carboxyl­ate
title_full Ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1H-pyrazole-5-carboxyl­ate
title_fullStr Ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1H-pyrazole-5-carboxyl­ate
title_full_unstemmed Ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1H-pyrazole-5-carboxyl­ate
title_short Ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1H-pyrazole-5-carboxyl­ate
title_sort ethyl 3-ferrocenyl-1-(pyridin-2-ylmeth­yl)-1h-pyrazole-5-carboxyl­ate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254307/
https://www.ncbi.nlm.nih.gov/pubmed/22259337
http://dx.doi.org/10.1107/S160053681105238X
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AT munyanezaapollinaire ethyl3ferrocenyl1pyridin2ylmethyl1hpyrazole5carboxylate
AT darkwajames ethyl3ferrocenyl1pyridin2ylmethyl1hpyrazole5carboxylate

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