Cargando…

catena-Poly[[bis­(μ-2-formyl-6-meth­oxy­phenolato-1:2κ(4) O (1),O (6):O (1),O (2))copper(II)sodium]-μ-tetra­fluorido­borate-1:1′κ(2) F:F′]

In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-meth­oxy­phenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Yu, Gao, Po, Yang, Jing-Lin, Hou, Hai-Ge, Gao, Ting
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254308/
https://www.ncbi.nlm.nih.gov/pubmed/22259338
http://dx.doi.org/10.1107/S1600536811051713
Descripción
Sumario:In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-meth­oxy­phenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetra­fluoridoborate anions. The tetra­fluoridoborate anion links the Na(+) ions, forming a one-dimensional structure along [001]. Three F atoms of the tetra­fluoridoborate anion are disordered over two sets of sites, with an occupancy ratio of 0.790 (11):0.210 (11).