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catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4) O (1),O (6):O (1),O (2))copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ(2) F:F′]
In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-methoxyphenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254308/ https://www.ncbi.nlm.nih.gov/pubmed/22259338 http://dx.doi.org/10.1107/S1600536811051713 |
| _version_ | 1782220829941039104 |
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| author | Yang, Yu Gao, Po Yang, Jing-Lin Hou, Hai-Ge Gao, Ting |
| author_facet | Yang, Yu Gao, Po Yang, Jing-Lin Hou, Hai-Ge Gao, Ting |
| author_sort | Yang, Yu |
| collection | PubMed |
| description | In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-methoxyphenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetrafluoridoborate anions. The tetrafluoridoborate anion links the Na(+) ions, forming a one-dimensional structure along [001]. Three F atoms of the tetrafluoridoborate anion are disordered over two sets of sites, with an occupancy ratio of 0.790 (11):0.210 (11). |
| format | Online Article Text |
| id | pubmed-3254308 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32543082012-01-18 catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4) O (1),O (6):O (1),O (2))copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ(2) F:F′] Yang, Yu Gao, Po Yang, Jing-Lin Hou, Hai-Ge Gao, Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title heterodinuclear complex, [CuNa(BF(4))(C(8)H(7)O(3))(2)](n), the Cu(II) ion is four-coordinated by four O atoms of two 2-formyl-6-methoxyphenolate ligands, giving rise to a square-planar geometry. The Na(+) ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetrafluoridoborate anions. The tetrafluoridoborate anion links the Na(+) ions, forming a one-dimensional structure along [001]. Three F atoms of the tetrafluoridoborate anion are disordered over two sets of sites, with an occupancy ratio of 0.790 (11):0.210 (11). International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254308/ /pubmed/22259338 http://dx.doi.org/10.1107/S1600536811051713 Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yang, Yu Gao, Po Yang, Jing-Lin Hou, Hai-Ge Gao, Ting catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4) O (1),O (6):O (1),O (2))copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ(2) F:F′] |
| title |
catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4)
O
(1),O
(6):O
(1),O
(2))copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ(2)
F:F′] |
| title_full |
catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4)
O
(1),O
(6):O
(1),O
(2))copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ(2)
F:F′] |
| title_fullStr |
catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4)
O
(1),O
(6):O
(1),O
(2))copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ(2)
F:F′] |
| title_full_unstemmed |
catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4)
O
(1),O
(6):O
(1),O
(2))copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ(2)
F:F′] |
| title_short |
catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4)
O
(1),O
(6):O
(1),O
(2))copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ(2)
F:F′] |
| title_sort | catena-poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ(4)
o
(1),o
(6):o
(1),o
(2))copper(ii)sodium]-μ-tetrafluoridoborate-1:1′κ(2)
f:f′] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254308/ https://www.ncbi.nlm.nih.gov/pubmed/22259338 http://dx.doi.org/10.1107/S1600536811051713 |
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