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Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate
The title compound, [Ni(4)(C(6)H(5)N(3)O)(2)(C(6)H(6)N(3)O)(2)(C(5)H(5)N)(4)](NO(3))(2), is a tetranuclear nickel complex containing a single-decker cation, located on an inversion center. The two unique Ni(II) cations are N,N′,N′′,O-chelated by carboximidamidate(2−) and carboximidamidate(1−) an...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254310/ https://www.ncbi.nlm.nih.gov/pubmed/22259341 http://dx.doi.org/10.1107/S1600536811052524 |
Sumario: | The title compound, [Ni(4)(C(6)H(5)N(3)O)(2)(C(6)H(6)N(3)O)(2)(C(5)H(5)N)(4)](NO(3))(2), is a tetranuclear nickel complex containing a single-decker cation, located on an inversion center. The two unique Ni(II) cations are N,N′,N′′,O-chelated by carboximidamidate(2−) and carboximidamidate(1−) anions, forming a distorted four-coordinate planar structure, while the other two Ni(II) atoms are N,N′,O,O′-chelated by the same bridging ligands and two pyridine molecules, affording six-coordinated metals in an octahedral geometry. The cation is isostructural with the complex crystallized with perchlorate counter-ions in place of nitrate. |
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