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Bis[μ(3)-N′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-N′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(II) dinitrate

The title compound, [Ni(4)(C(6)H(5)N(3)O)(2)(C(6)H(6)N(3)O)(2)(C(5)H(5)N)(4)](NO(3))(2), is a tetra­nuclear nickel complex containing a single-decker cation, located on an inversion center. The two unique Ni(II) cations are N,N′,N′′,O-chelated by carbox­imid­amid­ate(2−) and carboximidamidate(1−) an...

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Detalles Bibliográficos
Autores principales: Deng, Xiao-Hui, Ran, Jing-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254310/
https://www.ncbi.nlm.nih.gov/pubmed/22259341
http://dx.doi.org/10.1107/S1600536811052524
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author Deng, Xiao-Hui
Ran, Jing-Wen
author_facet Deng, Xiao-Hui
Ran, Jing-Wen
author_sort Deng, Xiao-Hui
collection PubMed
description The title compound, [Ni(4)(C(6)H(5)N(3)O)(2)(C(6)H(6)N(3)O)(2)(C(5)H(5)N)(4)](NO(3))(2), is a tetra­nuclear nickel complex containing a single-decker cation, located on an inversion center. The two unique Ni(II) cations are N,N′,N′′,O-chelated by carbox­imid­amid­ate(2−) and carboximidamidate(1−) anions, forming a distorted four-coordinate planar structure, while the other two Ni(II) atoms are N,N′,O,O′-chelated by the same bridging ligands and two pyridine mol­ecules, affording six-coordinated metals in an octa­hedral geometry. The cation is isostructural with the complex crystallized with perchlorate counter-ions in place of nitrate.
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spelling pubmed-32543102012-01-18 Bis[μ(3)-N′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-N′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(II) dinitrate Deng, Xiao-Hui Ran, Jing-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(4)(C(6)H(5)N(3)O)(2)(C(6)H(6)N(3)O)(2)(C(5)H(5)N)(4)](NO(3))(2), is a tetra­nuclear nickel complex containing a single-decker cation, located on an inversion center. The two unique Ni(II) cations are N,N′,N′′,O-chelated by carbox­imid­amid­ate(2−) and carboximidamidate(1−) anions, forming a distorted four-coordinate planar structure, while the other two Ni(II) atoms are N,N′,O,O′-chelated by the same bridging ligands and two pyridine mol­ecules, affording six-coordinated metals in an octa­hedral geometry. The cation is isostructural with the complex crystallized with perchlorate counter-ions in place of nitrate. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254310/ /pubmed/22259341 http://dx.doi.org/10.1107/S1600536811052524 Text en © Deng and Ran 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Xiao-Hui
Ran, Jing-Wen
Bis[μ(3)-N′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-N′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(II) dinitrate
title Bis[μ(3)-N′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-N′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(II) dinitrate
title_full Bis[μ(3)-N′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-N′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(II) dinitrate
title_fullStr Bis[μ(3)-N′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-N′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(II) dinitrate
title_full_unstemmed Bis[μ(3)-N′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-N′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(II) dinitrate
title_short Bis[μ(3)-N′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-N′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(II) dinitrate
title_sort bis[μ(3)-n′-oxidopyridine-2-carbox­imidamidato(2−)]bis­[μ(2)-n′-oxido­pyridine-2-carboximidamidato(1−)]tetra­pyridine­tetra­nickel(ii) dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254310/
https://www.ncbi.nlm.nih.gov/pubmed/22259341
http://dx.doi.org/10.1107/S1600536811052524
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