Cargando…
Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate
The title compound, [Ni(4)(C(6)H(5)N(3)O)(2)(C(6)H(6)N(3)O)(2)(C(5)H(5)N)(4)](NO(3))(2), is a tetranuclear nickel complex containing a single-decker cation, located on an inversion center. The two unique Ni(II) cations are N,N′,N′′,O-chelated by carboximidamidate(2−) and carboximidamidate(1−) an...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254310/ https://www.ncbi.nlm.nih.gov/pubmed/22259341 http://dx.doi.org/10.1107/S1600536811052524 |
_version_ | 1782220830427578368 |
---|---|
author | Deng, Xiao-Hui Ran, Jing-Wen |
author_facet | Deng, Xiao-Hui Ran, Jing-Wen |
author_sort | Deng, Xiao-Hui |
collection | PubMed |
description | The title compound, [Ni(4)(C(6)H(5)N(3)O)(2)(C(6)H(6)N(3)O)(2)(C(5)H(5)N)(4)](NO(3))(2), is a tetranuclear nickel complex containing a single-decker cation, located on an inversion center. The two unique Ni(II) cations are N,N′,N′′,O-chelated by carboximidamidate(2−) and carboximidamidate(1−) anions, forming a distorted four-coordinate planar structure, while the other two Ni(II) atoms are N,N′,O,O′-chelated by the same bridging ligands and two pyridine molecules, affording six-coordinated metals in an octahedral geometry. The cation is isostructural with the complex crystallized with perchlorate counter-ions in place of nitrate. |
format | Online Article Text |
id | pubmed-3254310 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543102012-01-18 Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate Deng, Xiao-Hui Ran, Jing-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(4)(C(6)H(5)N(3)O)(2)(C(6)H(6)N(3)O)(2)(C(5)H(5)N)(4)](NO(3))(2), is a tetranuclear nickel complex containing a single-decker cation, located on an inversion center. The two unique Ni(II) cations are N,N′,N′′,O-chelated by carboximidamidate(2−) and carboximidamidate(1−) anions, forming a distorted four-coordinate planar structure, while the other two Ni(II) atoms are N,N′,O,O′-chelated by the same bridging ligands and two pyridine molecules, affording six-coordinated metals in an octahedral geometry. The cation is isostructural with the complex crystallized with perchlorate counter-ions in place of nitrate. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254310/ /pubmed/22259341 http://dx.doi.org/10.1107/S1600536811052524 Text en © Deng and Ran 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Deng, Xiao-Hui Ran, Jing-Wen Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate |
title | Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate |
title_full | Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate |
title_fullStr | Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate |
title_full_unstemmed | Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate |
title_short | Bis[μ(3)-N′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-N′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(II) dinitrate |
title_sort | bis[μ(3)-n′-oxidopyridine-2-carboximidamidato(2−)]bis[μ(2)-n′-oxidopyridine-2-carboximidamidato(1−)]tetrapyridinetetranickel(ii) dinitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254310/ https://www.ncbi.nlm.nih.gov/pubmed/22259341 http://dx.doi.org/10.1107/S1600536811052524 |
work_keys_str_mv | AT dengxiaohui bism3noxidopyridine2carboximidamidato2bism2noxidopyridine2carboximidamidato1tetrapyridinetetranickeliidinitrate AT ranjingwen bism3noxidopyridine2carboximidamidato2bism2noxidopyridine2carboximidamidato1tetrapyridinetetranickeliidinitrate |