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Pentaaqua(5-carboxypyridine-2-carboxylato-κ(2) N,O (2))(pyridine-2,5-dicarboxylato-κ(2) N,O (2))cerium(III) tetrahydrate
In the title compound, [Ce(C(7)H(3)NO(4))(C(7)H(4)NO(4))(H(2)O)(5)]·4H(2)O, the Ce(3+) ion is nine-coordinated by two O atoms and two N atoms from one single and from one double deprotonated pyridine-2,5-dicarboxylate ligand and five water molecules in a distorted monocapped square-antiprismatic...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254311/ https://www.ncbi.nlm.nih.gov/pubmed/22259342 http://dx.doi.org/10.1107/S1600536811052688 |
| _version_ | 1782220830672945152 |
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| author | Ma, Ning Zhang, Tong Yang, Guang-Rui |
| author_facet | Ma, Ning Zhang, Tong Yang, Guang-Rui |
| author_sort | Ma, Ning |
| collection | PubMed |
| description | In the title compound, [Ce(C(7)H(3)NO(4))(C(7)H(4)NO(4))(H(2)O)(5)]·4H(2)O, the Ce(3+) ion is nine-coordinated by two O atoms and two N atoms from one single and from one double deprotonated pyridine-2,5-dicarboxylate ligand and five water molecules in a distorted monocapped square-antiprismatic geometry. In the crystal, extensive O—H⋯O hydrogen-bonding interactions result in a three-dimensional supramolecular architecture. |
| format | Online Article Text |
| id | pubmed-3254311 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32543112012-01-18 Pentaaqua(5-carboxypyridine-2-carboxylato-κ(2) N,O (2))(pyridine-2,5-dicarboxylato-κ(2) N,O (2))cerium(III) tetrahydrate Ma, Ning Zhang, Tong Yang, Guang-Rui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ce(C(7)H(3)NO(4))(C(7)H(4)NO(4))(H(2)O)(5)]·4H(2)O, the Ce(3+) ion is nine-coordinated by two O atoms and two N atoms from one single and from one double deprotonated pyridine-2,5-dicarboxylate ligand and five water molecules in a distorted monocapped square-antiprismatic geometry. In the crystal, extensive O—H⋯O hydrogen-bonding interactions result in a three-dimensional supramolecular architecture. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254311/ /pubmed/22259342 http://dx.doi.org/10.1107/S1600536811052688 Text en © Ma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ma, Ning Zhang, Tong Yang, Guang-Rui Pentaaqua(5-carboxypyridine-2-carboxylato-κ(2) N,O (2))(pyridine-2,5-dicarboxylato-κ(2) N,O (2))cerium(III) tetrahydrate |
| title | Pentaaqua(5-carboxypyridine-2-carboxylato-κ(2)
N,O
(2))(pyridine-2,5-dicarboxylato-κ(2)
N,O
(2))cerium(III) tetrahydrate |
| title_full | Pentaaqua(5-carboxypyridine-2-carboxylato-κ(2)
N,O
(2))(pyridine-2,5-dicarboxylato-κ(2)
N,O
(2))cerium(III) tetrahydrate |
| title_fullStr | Pentaaqua(5-carboxypyridine-2-carboxylato-κ(2)
N,O
(2))(pyridine-2,5-dicarboxylato-κ(2)
N,O
(2))cerium(III) tetrahydrate |
| title_full_unstemmed | Pentaaqua(5-carboxypyridine-2-carboxylato-κ(2)
N,O
(2))(pyridine-2,5-dicarboxylato-κ(2)
N,O
(2))cerium(III) tetrahydrate |
| title_short | Pentaaqua(5-carboxypyridine-2-carboxylato-κ(2)
N,O
(2))(pyridine-2,5-dicarboxylato-κ(2)
N,O
(2))cerium(III) tetrahydrate |
| title_sort | pentaaqua(5-carboxypyridine-2-carboxylato-κ(2)
n,o
(2))(pyridine-2,5-dicarboxylato-κ(2)
n,o
(2))cerium(iii) tetrahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254311/ https://www.ncbi.nlm.nih.gov/pubmed/22259342 http://dx.doi.org/10.1107/S1600536811052688 |
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