Tetra­kis(μ-4-azido­benzoato-κ(2) O:O′)bis­[(N,N-dimethyl­formamide-κO)copper(II)]

The binuclear title compound, [Cu(2)(C(7)H(4)N(3)O(2))(4)(C(3)H(7)NO)(2)], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu⋯Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The Cu(II) cation is coordinated by four carboxyl...

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Detalles Bibliográficos
Autor principal: Wang, Aidong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254312/
https://www.ncbi.nlm.nih.gov/pubmed/22259343
http://dx.doi.org/10.1107/S1600536811050999
Descripción
Sumario:The binuclear title compound, [Cu(2)(C(7)H(4)N(3)O(2))(4)(C(3)H(7)NO)(2)], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu⋯Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The Cu(II) cation is coordinated by four carboxyl­ate O atoms from four 4-azido­benzoate ligands, and one O atom from a dimethyl­formamide mol­ecule, forming an overall distorted octahedral geometry when the Cu⋯Cu bond is also considered.

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