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Tetrakis(μ-4-azidobenzoato-κ(2) O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
The binuclear title compound, [Cu(2)(C(7)H(4)N(3)O(2))(4)(C(3)H(7)NO)(2)], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu⋯Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The Cu(II) cation is coordinated by four carboxyl...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254312/ https://www.ncbi.nlm.nih.gov/pubmed/22259343 http://dx.doi.org/10.1107/S1600536811050999 |
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| author | Wang, Aidong |
| author_facet | Wang, Aidong |
| author_sort | Wang, Aidong |
| collection | PubMed |
| description | The binuclear title compound, [Cu(2)(C(7)H(4)N(3)O(2))(4)(C(3)H(7)NO)(2)], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu⋯Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The Cu(II) cation is coordinated by four carboxylate O atoms from four 4-azidobenzoate ligands, and one O atom from a dimethylformamide molecule, forming an overall distorted octahedral geometry when the Cu⋯Cu bond is also considered. |
| format | Online Article Text |
| id | pubmed-3254312 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32543122012-01-18 Tetrakis(μ-4-azidobenzoato-κ(2) O:O′)bis[(N,N-dimethylformamide-κO)copper(II)] Wang, Aidong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear title compound, [Cu(2)(C(7)H(4)N(3)O(2))(4)(C(3)H(7)NO)(2)], is a discrete metal–organic compound having a paddle-wheel-type structure. The Cu⋯Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The Cu(II) cation is coordinated by four carboxylate O atoms from four 4-azidobenzoate ligands, and one O atom from a dimethylformamide molecule, forming an overall distorted octahedral geometry when the Cu⋯Cu bond is also considered. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254312/ /pubmed/22259343 http://dx.doi.org/10.1107/S1600536811050999 Text en © Aidong Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Aidong Tetrakis(μ-4-azidobenzoato-κ(2) O:O′)bis[(N,N-dimethylformamide-κO)copper(II)] |
| title | Tetrakis(μ-4-azidobenzoato-κ(2)
O:O′)bis[(N,N-dimethylformamide-κO)copper(II)] |
| title_full | Tetrakis(μ-4-azidobenzoato-κ(2)
O:O′)bis[(N,N-dimethylformamide-κO)copper(II)] |
| title_fullStr | Tetrakis(μ-4-azidobenzoato-κ(2)
O:O′)bis[(N,N-dimethylformamide-κO)copper(II)] |
| title_full_unstemmed | Tetrakis(μ-4-azidobenzoato-κ(2)
O:O′)bis[(N,N-dimethylformamide-κO)copper(II)] |
| title_short | Tetrakis(μ-4-azidobenzoato-κ(2)
O:O′)bis[(N,N-dimethylformamide-κO)copper(II)] |
| title_sort | tetrakis(μ-4-azidobenzoato-κ(2)
o:o′)bis[(n,n-dimethylformamide-κo)copper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254312/ https://www.ncbi.nlm.nih.gov/pubmed/22259343 http://dx.doi.org/10.1107/S1600536811050999 |
| work_keys_str_mv | AT wangaidong tetrakism4azidobenzoatok2oobisnndimethylformamidekocopperii |