{N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)

In the title compound, [HgBr(2)(C(15)H(17)N(5))], the Hg(II) ion is tetra­hedrally coordinated by two N atoms of the N-[1-(1H-benzimidazol-2-yl)ethyl­idene-κN]-3-(1H-imidazol-1-yl)propan-1-amine ligand, and two bromide anions. Inter­molecular benzimidazole–imidazole N—H⋯N hydrogen bonds link the mol...

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Detalles Bibliográficos
Autores principales: Wang, Qing, Fu, Zhong-Ye, Yu, Liang-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254313/
https://www.ncbi.nlm.nih.gov/pubmed/22259344
http://dx.doi.org/10.1107/S1600536811051166
Descripción
Sumario:In the title compound, [HgBr(2)(C(15)H(17)N(5))], the Hg(II) ion is tetra­hedrally coordinated by two N atoms of the N-[1-(1H-benzimidazol-2-yl)ethyl­idene-κN]-3-(1H-imidazol-1-yl)propan-1-amine ligand, and two bromide anions. Inter­molecular benzimidazole–imidazole N—H⋯N hydrogen bonds link the mol­ecules into helical chains along the b-axis direction and C—H⋯Br hydrogen bonds link these chains into layers parallel to the bc plane.

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