{N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)

In the title compound, [HgBr(2)(C(15)H(17)N(5))], the Hg(II) ion is tetra­hedrally coordinated by two N atoms of the N-[1-(1H-benzimidazol-2-yl)ethyl­idene-κN]-3-(1H-imidazol-1-yl)propan-1-amine ligand, and two bromide anions. Inter­molecular benzimidazole–imidazole N—H⋯N hydrogen bonds link the mol...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Qing, Fu, Zhong-Ye, Yu, Liang-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254313/
https://www.ncbi.nlm.nih.gov/pubmed/22259344
http://dx.doi.org/10.1107/S1600536811051166
_version_ 1782220831134318592
author Wang, Qing
Fu, Zhong-Ye
Yu, Liang-Min
author_facet Wang, Qing
Fu, Zhong-Ye
Yu, Liang-Min
author_sort Wang, Qing
collection PubMed
description In the title compound, [HgBr(2)(C(15)H(17)N(5))], the Hg(II) ion is tetra­hedrally coordinated by two N atoms of the N-[1-(1H-benzimidazol-2-yl)ethyl­idene-κN]-3-(1H-imidazol-1-yl)propan-1-amine ligand, and two bromide anions. Inter­molecular benzimidazole–imidazole N—H⋯N hydrogen bonds link the mol­ecules into helical chains along the b-axis direction and C—H⋯Br hydrogen bonds link these chains into layers parallel to the bc plane.
format Online
Article
Text
id pubmed-3254313
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32543132012-01-18 {N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II) Wang, Qing Fu, Zhong-Ye Yu, Liang-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [HgBr(2)(C(15)H(17)N(5))], the Hg(II) ion is tetra­hedrally coordinated by two N atoms of the N-[1-(1H-benzimidazol-2-yl)ethyl­idene-κN]-3-(1H-imidazol-1-yl)propan-1-amine ligand, and two bromide anions. Inter­molecular benzimidazole–imidazole N—H⋯N hydrogen bonds link the mol­ecules into helical chains along the b-axis direction and C—H⋯Br hydrogen bonds link these chains into layers parallel to the bc plane. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254313/ /pubmed/22259344 http://dx.doi.org/10.1107/S1600536811051166 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Qing
Fu, Zhong-Ye
Yu, Liang-Min
{N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)
title {N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)
title_full {N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)
title_fullStr {N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)
title_full_unstemmed {N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)
title_short {N-[1-(1H-Benzimidazol-2-yl)ethyl­idene-κN (3)]-3-(1H-imidazol-1-yl)propan-1-amine-κN}dibromidomercury(II)
title_sort {n-[1-(1h-benzimidazol-2-yl)ethyl­idene-κn (3)]-3-(1h-imidazol-1-yl)propan-1-amine-κn}dibromidomercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254313/
https://www.ncbi.nlm.nih.gov/pubmed/22259344
http://dx.doi.org/10.1107/S1600536811051166
work_keys_str_mv AT wangqing n11hbenzimidazol2ylethylidenekn331himidazol1ylpropan1aminekndibromidomercuryii
AT fuzhongye n11hbenzimidazol2ylethylidenekn331himidazol1ylpropan1aminekndibromidomercuryii
AT yuliangmin n11hbenzimidazol2ylethylidenekn331himidazol1ylpropan1aminekndibromidomercuryii

Ejemplares similares