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cis-Dichloridobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II)

In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octa­hedral environment defined by four N atoms of two chelating di-2-pyridyl­amine (dpa) ligands and two Cl(−) anions. In the crystal, the dpa ligands are not planar, the d...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254314/
https://www.ncbi.nlm.nih.gov/pubmed/22259345
http://dx.doi.org/10.1107/S1600536811052834
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octa­hedral environment defined by four N atoms of two chelating di-2-pyridyl­amine (dpa) ligands and two Cl(−) anions. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.3 (2) and 30.9 (2)°. The complex mol­ecules are stacked in columns along the c axis and are connected by inter­molecular N—H⋯Cl hydrogen bonds, forming a three-dimensional network. Weak inter- and intra­molecular π–π inter­actions are present between the pyridine rings, the shortest centroid—centroid distance being 4.406 (3) Å.
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spelling pubmed-32543142012-01-18 cis-Dichloridobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octa­hedral environment defined by four N atoms of two chelating di-2-pyridyl­amine (dpa) ligands and two Cl(−) anions. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.3 (2) and 30.9 (2)°. The complex mol­ecules are stacked in columns along the c axis and are connected by inter­molecular N—H⋯Cl hydrogen bonds, forming a three-dimensional network. Weak inter- and intra­molecular π–π inter­actions are present between the pyridine rings, the shortest centroid—centroid distance being 4.406 (3) Å. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254314/ /pubmed/22259345 http://dx.doi.org/10.1107/S1600536811052834 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
cis-Dichloridobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II)
title cis-Dichloridobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II)
title_full cis-Dichloridobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II)
title_fullStr cis-Dichloridobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II)
title_full_unstemmed cis-Dichloridobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II)
title_short cis-Dichloridobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II)
title_sort cis-dichloridobis(di-2-pyridyl­amine-κ(2) n,n′)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254314/
https://www.ncbi.nlm.nih.gov/pubmed/22259345
http://dx.doi.org/10.1107/S1600536811052834
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