Cargando…
cis-Dichloridobis(di-2-pyridylamine-κ(2) N,N′)manganese(II)
In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octahedral environment defined by four N atoms of two chelating di-2-pyridylamine (dpa) ligands and two Cl(−) anions. In the crystal, the dpa ligands are not planar, the d...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254314/ https://www.ncbi.nlm.nih.gov/pubmed/22259345 http://dx.doi.org/10.1107/S1600536811052834 |
_version_ | 1782220831370248192 |
---|---|
author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octahedral environment defined by four N atoms of two chelating di-2-pyridylamine (dpa) ligands and two Cl(−) anions. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.3 (2) and 30.9 (2)°. The complex molecules are stacked in columns along the c axis and are connected by intermolecular N—H⋯Cl hydrogen bonds, forming a three-dimensional network. Weak inter- and intramolecular π–π interactions are present between the pyridine rings, the shortest centroid—centroid distance being 4.406 (3) Å. |
format | Online Article Text |
id | pubmed-3254314 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543142012-01-18 cis-Dichloridobis(di-2-pyridylamine-κ(2) N,N′)manganese(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octahedral environment defined by four N atoms of two chelating di-2-pyridylamine (dpa) ligands and two Cl(−) anions. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.3 (2) and 30.9 (2)°. The complex molecules are stacked in columns along the c axis and are connected by intermolecular N—H⋯Cl hydrogen bonds, forming a three-dimensional network. Weak inter- and intramolecular π–π interactions are present between the pyridine rings, the shortest centroid—centroid distance being 4.406 (3) Å. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254314/ /pubmed/22259345 http://dx.doi.org/10.1107/S1600536811052834 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang cis-Dichloridobis(di-2-pyridylamine-κ(2) N,N′)manganese(II) |
title |
cis-Dichloridobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) |
title_full |
cis-Dichloridobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) |
title_fullStr |
cis-Dichloridobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) |
title_full_unstemmed |
cis-Dichloridobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) |
title_short |
cis-Dichloridobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) |
title_sort | cis-dichloridobis(di-2-pyridylamine-κ(2)
n,n′)manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254314/ https://www.ncbi.nlm.nih.gov/pubmed/22259345 http://dx.doi.org/10.1107/S1600536811052834 |
work_keys_str_mv | AT hakwang cisdichloridobisdi2pyridylaminek2nnmanganeseii |