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trans-Bis(ethylenediamine-κ(2) N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II)
In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octahedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatoria...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254316/ https://www.ncbi.nlm.nih.gov/pubmed/22259347 http://dx.doi.org/10.1107/S1600536811051658 |
Sumario: | In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octahedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatorial bond distances between the Cu(II) ion and the N atoms of the ethylenediamine ligand as a consequence of the Jahn–Teller effect. The molecular conformation is stabilized by intramolecular N—H⋯O hydrogen bonds. In the crystal, molecules are connected by intermolecular N—H⋯O hydrogen bonds into chains running along the a axis. |
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