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trans-Bis(ethyl­enediamine-κ(2) N,N′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κN)copper(II)

In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octa­hedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatoria...

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Detalles Bibliográficos
Autores principales: Dege, Necmi, Demirtaş, Güneş, Içbudak, Hasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254316/
https://www.ncbi.nlm.nih.gov/pubmed/22259347
http://dx.doi.org/10.1107/S1600536811051658
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author Dege, Necmi
Demirtaş, Güneş
Içbudak, Hasan
author_facet Dege, Necmi
Demirtaş, Güneş
Içbudak, Hasan
author_sort Dege, Necmi
collection PubMed
description In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octa­hedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatorial bond distances between the Cu(II) ion and the N atoms of the ethyl­enediamine ligand as a consequence of the Jahn–Teller effect. The mol­ecular conformation is stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal, mol­ecules are connected by inter­molecular N—H⋯O hydrogen bonds into chains running along the a axis.
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spelling pubmed-32543162012-01-18 trans-Bis(ethyl­enediamine-κ(2) N,N′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κN)copper(II) Dege, Necmi Demirtaş, Güneş Içbudak, Hasan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octa­hedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatorial bond distances between the Cu(II) ion and the N atoms of the ethyl­enediamine ligand as a consequence of the Jahn–Teller effect. The mol­ecular conformation is stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal, mol­ecules are connected by inter­molecular N—H⋯O hydrogen bonds into chains running along the a axis. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254316/ /pubmed/22259347 http://dx.doi.org/10.1107/S1600536811051658 Text en © Dege et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dege, Necmi
Demirtaş, Güneş
Içbudak, Hasan
trans-Bis(ethyl­enediamine-κ(2) N,N′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κN)copper(II)
title trans-Bis(ethyl­enediamine-κ(2) N,N′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κN)copper(II)
title_full trans-Bis(ethyl­enediamine-κ(2) N,N′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κN)copper(II)
title_fullStr trans-Bis(ethyl­enediamine-κ(2) N,N′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κN)copper(II)
title_full_unstemmed trans-Bis(ethyl­enediamine-κ(2) N,N′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κN)copper(II)
title_short trans-Bis(ethyl­enediamine-κ(2) N,N′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κN)copper(II)
title_sort trans-bis(ethyl­enediamine-κ(2) n,n′)bis­(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathia­zin-3-ido-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254316/
https://www.ncbi.nlm.nih.gov/pubmed/22259347
http://dx.doi.org/10.1107/S1600536811051658
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