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trans-Bis(ethylenediamine-κ(2) N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II)
In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octahedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatoria...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254316/ https://www.ncbi.nlm.nih.gov/pubmed/22259347 http://dx.doi.org/10.1107/S1600536811051658 |
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author | Dege, Necmi Demirtaş, Güneş Içbudak, Hasan |
author_facet | Dege, Necmi Demirtaş, Güneş Içbudak, Hasan |
author_sort | Dege, Necmi |
collection | PubMed |
description | In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octahedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatorial bond distances between the Cu(II) ion and the N atoms of the ethylenediamine ligand as a consequence of the Jahn–Teller effect. The molecular conformation is stabilized by intramolecular N—H⋯O hydrogen bonds. In the crystal, molecules are connected by intermolecular N—H⋯O hydrogen bonds into chains running along the a axis. |
format | Online Article Text |
id | pubmed-3254316 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543162012-01-18 trans-Bis(ethylenediamine-κ(2) N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II) Dege, Necmi Demirtaş, Güneş Içbudak, Hasan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(4)H(4)NO(4)S)(2)(C(2)H(8)N(2))(2)], the Cu(2+) ion resides on a centre of symmetry. The environment of Cu(2+) ion is a distorted octahedron. The axial bond lengths between the Cu(II) ion and the N atoms are considerably longer than the equatorial bond distances between the Cu(II) ion and the N atoms of the ethylenediamine ligand as a consequence of the Jahn–Teller effect. The molecular conformation is stabilized by intramolecular N—H⋯O hydrogen bonds. In the crystal, molecules are connected by intermolecular N—H⋯O hydrogen bonds into chains running along the a axis. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254316/ /pubmed/22259347 http://dx.doi.org/10.1107/S1600536811051658 Text en © Dege et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dege, Necmi Demirtaş, Güneş Içbudak, Hasan trans-Bis(ethylenediamine-κ(2) N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II) |
title |
trans-Bis(ethylenediamine-κ(2)
N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II) |
title_full |
trans-Bis(ethylenediamine-κ(2)
N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II) |
title_fullStr |
trans-Bis(ethylenediamine-κ(2)
N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II) |
title_full_unstemmed |
trans-Bis(ethylenediamine-κ(2)
N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II) |
title_short |
trans-Bis(ethylenediamine-κ(2)
N,N′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κN)copper(II) |
title_sort | trans-bis(ethylenediamine-κ(2)
n,n′)bis(6-methyl-2,2,4-trioxo-3,4-dihydro-1,2λ(6),3-oxathiazin-3-ido-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254316/ https://www.ncbi.nlm.nih.gov/pubmed/22259347 http://dx.doi.org/10.1107/S1600536811051658 |
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