Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I)

The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent mol­ecules in the asymmetric unit in which the thio­phene fragments are disordered over two sets of sites with 0.537 (10):0.463 (10) and 0.701 (9):0.299 (9) occupancy ratios. In both cases, the thio­phene ring is rotated by...

Descripción completa

Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254317/
https://www.ncbi.nlm.nih.gov/pubmed/22259348
http://dx.doi.org/10.1107/S1600536811052536
Descripción
Sumario:The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent mol­ecules in the asymmetric unit in which the thio­phene fragments are disordered over two sets of sites with 0.537 (10):0.463 (10) and 0.701 (9):0.299 (9) occupancy ratios. In both cases, the thio­phene ring is rotated by approximately 180° for the second component. Important geometrical parameters include Au—P = 2.235 (2) and 2.237 (2) Å, Au—Cl = 2.286 (2) and 2.292 (2) Å, and P—Au—Cl = 177.39 (8) and 172.63 (7)°. Weak inter­molecular C—H⋯Cl inter­actions are observed in the crystal structure.

Ejemplares similares