Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I)

The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent mol­ecules in the asymmetric unit in which the thio­phene fragments are disordered over two sets of sites with 0.537 (10):0.463 (10) and 0.701 (9):0.299 (9) occupancy ratios. In both cases, the thio­phene ring is rotated by...

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Detalles Bibliográficos
Autores principales: Chiririwa, Haleden, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254317/
https://www.ncbi.nlm.nih.gov/pubmed/22259348
http://dx.doi.org/10.1107/S1600536811052536
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author Chiririwa, Haleden
Muller, Alfred
author_facet Chiririwa, Haleden
Muller, Alfred
author_sort Chiririwa, Haleden
collection PubMed
description The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent mol­ecules in the asymmetric unit in which the thio­phene fragments are disordered over two sets of sites with 0.537 (10):0.463 (10) and 0.701 (9):0.299 (9) occupancy ratios. In both cases, the thio­phene ring is rotated by approximately 180° for the second component. Important geometrical parameters include Au—P = 2.235 (2) and 2.237 (2) Å, Au—Cl = 2.286 (2) and 2.292 (2) Å, and P—Au—Cl = 177.39 (8) and 172.63 (7)°. Weak inter­molecular C—H⋯Cl inter­actions are observed in the crystal structure.
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spelling pubmed-32543172012-01-18 Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I) Chiririwa, Haleden Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent mol­ecules in the asymmetric unit in which the thio­phene fragments are disordered over two sets of sites with 0.537 (10):0.463 (10) and 0.701 (9):0.299 (9) occupancy ratios. In both cases, the thio­phene ring is rotated by approximately 180° for the second component. Important geometrical parameters include Au—P = 2.235 (2) and 2.237 (2) Å, Au—Cl = 2.286 (2) and 2.292 (2) Å, and P—Au—Cl = 177.39 (8) and 172.63 (7)°. Weak inter­molecular C—H⋯Cl inter­actions are observed in the crystal structure. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254317/ /pubmed/22259348 http://dx.doi.org/10.1107/S1600536811052536 Text en © Chiririwa and Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chiririwa, Haleden
Muller, Alfred
Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I)
title Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I)
title_full Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I)
title_fullStr Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I)
title_full_unstemmed Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I)
title_short Chlorido{N-[(E)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κP}gold(I)
title_sort chlorido{n-[(e)-2-(diphenyl­phosphan­yl)benzyl­idene]-2-(thio­phen-2-yl)ethan­amine-κp}gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254317/
https://www.ncbi.nlm.nih.gov/pubmed/22259348
http://dx.doi.org/10.1107/S1600536811052536
work_keys_str_mv AT chiririwahaleden chloridone2diphenylphosphanylbenzylidene2thiophen2ylethanaminekpgoldi
AT mulleralfred chloridone2diphenylphosphanylbenzylidene2thiophen2ylethanaminekpgoldi

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