Cargando…
Bis[1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium)] β-octamolybdate
In the title compound, (C(14)H(16)N(4))(2)[Mo(8)O(26)], the β-octamolybdate anion is centrosymmetric. N—H⋯O hydrogen bonds link the diimidazolium cations and the polyoxidoanions into a chain structure along [100]. π–π interactions between the imidazole rings and between the imidazole and benzene r...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254318/ https://www.ncbi.nlm.nih.gov/pubmed/22259350 http://dx.doi.org/10.1107/S1600536811053050 |
| _version_ | 1782220832299286528 |
|---|---|
| author | Wang, Xiao-Dan Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng |
| author_facet | Wang, Xiao-Dan Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng |
| author_sort | Wang, Xiao-Dan |
| collection | PubMed |
| description | In the title compound, (C(14)H(16)N(4))(2)[Mo(8)O(26)], the β-octamolybdate anion is centrosymmetric. N—H⋯O hydrogen bonds link the diimidazolium cations and the polyoxidoanions into a chain structure along [100]. π–π interactions between the imidazole rings and between the imidazole and benzene rings [centroid–centroid distances = 3.611 (2) and 3.689 (3) Å, respectively] connect the chains. |
| format | Online Article Text |
| id | pubmed-3254318 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32543182012-01-18 Bis[1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium)] β-octamolybdate Wang, Xiao-Dan Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(14)H(16)N(4))(2)[Mo(8)O(26)], the β-octamolybdate anion is centrosymmetric. N—H⋯O hydrogen bonds link the diimidazolium cations and the polyoxidoanions into a chain structure along [100]. π–π interactions between the imidazole rings and between the imidazole and benzene rings [centroid–centroid distances = 3.611 (2) and 3.689 (3) Å, respectively] connect the chains. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254318/ /pubmed/22259350 http://dx.doi.org/10.1107/S1600536811053050 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Xiao-Dan Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng Bis[1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium)] β-octamolybdate |
| title | Bis[1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium)] β-octamolybdate |
| title_full | Bis[1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium)] β-octamolybdate |
| title_fullStr | Bis[1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium)] β-octamolybdate |
| title_full_unstemmed | Bis[1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium)] β-octamolybdate |
| title_short | Bis[1,1′-(1,3-phenylenedimethylene)di(1H-imidazol-3-ium)] β-octamolybdate |
| title_sort | bis[1,1′-(1,3-phenylenedimethylene)di(1h-imidazol-3-ium)] β-octamolybdate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254318/ https://www.ncbi.nlm.nih.gov/pubmed/22259350 http://dx.doi.org/10.1107/S1600536811053050 |
| work_keys_str_mv | AT wangxiaodan bis1113phenylenedimethylenedi1himidazol3iumboctamolybdate AT houguangfeng bis1113phenylenedimethylenedi1himidazol3iumboctamolybdate AT yuyinghui bis1113phenylenedimethylenedi1himidazol3iumboctamolybdate AT gaojinsheng bis1113phenylenedimethylenedi1himidazol3iumboctamolybdate |