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Aquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate
The asymmetric unit of the title compound, [Cu(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)]·0.5C(6)H(6)N(2)O·3H(2)O, contains two aquabis(4-fluorobenzoato)bis(nicotinamide)copper(II) molecules, one nicotinamide solvent molecule and six water molecules. The Cu(II) ion is coordinated by two O a...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254320/ https://www.ncbi.nlm.nih.gov/pubmed/22259352 http://dx.doi.org/10.1107/S1600536811053116 |
Sumario: | The asymmetric unit of the title compound, [Cu(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)]·0.5C(6)H(6)N(2)O·3H(2)O, contains two aquabis(4-fluorobenzoato)bis(nicotinamide)copper(II) molecules, one nicotinamide solvent molecule and six water molecules. The Cu(II) ion is coordinated by two O atoms from two 4-fluorobenzoate ligands, two N atoms from two nicotinamide ligands and one water O atom in a distorted square-pyramidal geometry. In the crystal, O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds consolidate the crystal packing, which also exhibits π–π interactions between the aromatic rings [centroid–centroid distances 3.692 (2)–3.794 (2) Å]. |
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