Aqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate

The asymmetric unit of the title compound, [Cu(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)]·0.5C(6)H(6)N(2)O·3H(2)O, contains two aqua­bis­(4-fluoro­benzoato)bis­(nicotinamide)­copper(II) mol­ecules, one nicotinamide solvent mol­ecule and six water mol­ecules. The Cu(II) ion is coordinated by two O a...

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Autores principales: Necefoğlu, Hacali, Özbek, Füreya Elif, Öztürk, Vijdan, Adıgüzel, Vedat, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254320/
https://www.ncbi.nlm.nih.gov/pubmed/22259352
http://dx.doi.org/10.1107/S1600536811053116
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author Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description The asymmetric unit of the title compound, [Cu(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)]·0.5C(6)H(6)N(2)O·3H(2)O, contains two aqua­bis­(4-fluoro­benzoato)bis­(nicotinamide)­copper(II) mol­ecules, one nicotinamide solvent mol­ecule and six water mol­ecules. The Cu(II) ion is coordinated by two O atoms from two 4-fluoro­benzoate ligands, two N atoms from two nicotinamide ligands and one water O atom in a distorted square-pyramidal geometry. In the crystal, O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds consolidate the crystal packing, which also exhibits π–π inter­actions between the aromatic rings [centroid–centroid distances 3.692 (2)–3.794 (2) Å].
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spelling pubmed-32543202012-01-18 Aqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate Necefoğlu, Hacali Özbek, Füreya Elif Öztürk, Vijdan Adıgüzel, Vedat Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)]·0.5C(6)H(6)N(2)O·3H(2)O, contains two aqua­bis­(4-fluoro­benzoato)bis­(nicotinamide)­copper(II) mol­ecules, one nicotinamide solvent mol­ecule and six water mol­ecules. The Cu(II) ion is coordinated by two O atoms from two 4-fluoro­benzoate ligands, two N atoms from two nicotinamide ligands and one water O atom in a distorted square-pyramidal geometry. In the crystal, O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds consolidate the crystal packing, which also exhibits π–π inter­actions between the aromatic rings [centroid–centroid distances 3.692 (2)–3.794 (2) Å]. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254320/ /pubmed/22259352 http://dx.doi.org/10.1107/S1600536811053116 Text en © Necefoğlu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Özbek, Füreya Elif
Öztürk, Vijdan
Adıgüzel, Vedat
Hökelek, Tuncer
Aqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate
title Aqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate
title_full Aqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate
title_fullStr Aqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate
title_full_unstemmed Aqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate
title_short Aqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))copper(II) nicotinamide hemisolvate trihydrate
title_sort aqua­bis­(4-fluoro­benzoato-κo)bis­(nicotinamide-κn (1))copper(ii) nicotinamide hemisolvate trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254320/
https://www.ncbi.nlm.nih.gov/pubmed/22259352
http://dx.doi.org/10.1107/S1600536811053116
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