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trans-Bis(acridine-κN)dichloridopalladium(II)

In the title complex, [PdCl(2)(C(13)H(9)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment by two N atoms from two acridine ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex a...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254321/
https://www.ncbi.nlm.nih.gov/pubmed/22259353
http://dx.doi.org/10.1107/S1600536811053335
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [PdCl(2)(C(13)H(9)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment by two N atoms from two acridine ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex and the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and the acridine ligand is 84.66 (6)°. In the crystal, the complex mol­ecules are stacked in columns along the a axis connected by C—H⋯Cl hydrogen bonds, forming chains along [110]. In the columns, numerous inter­molecular π–π inter­actions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.722 (4) Å.
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spelling pubmed-32543212012-01-18 trans-Bis(acridine-κN)dichloridopalladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdCl(2)(C(13)H(9)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment by two N atoms from two acridine ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex and the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and the acridine ligand is 84.66 (6)°. In the crystal, the complex mol­ecules are stacked in columns along the a axis connected by C—H⋯Cl hydrogen bonds, forming chains along [110]. In the columns, numerous inter­molecular π–π inter­actions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.722 (4) Å. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254321/ /pubmed/22259353 http://dx.doi.org/10.1107/S1600536811053335 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
trans-Bis(acridine-κN)dichloridopalladium(II)
title trans-Bis(acridine-κN)dichloridopalladium(II)
title_full trans-Bis(acridine-κN)dichloridopalladium(II)
title_fullStr trans-Bis(acridine-κN)dichloridopalladium(II)
title_full_unstemmed trans-Bis(acridine-κN)dichloridopalladium(II)
title_short trans-Bis(acridine-κN)dichloridopalladium(II)
title_sort trans-bis(acridine-κn)dichloridopalladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254321/
https://www.ncbi.nlm.nih.gov/pubmed/22259353
http://dx.doi.org/10.1107/S1600536811053335
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