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trans-Bis(acridine-κN)dichloridopalladium(II)
In the title complex, [PdCl(2)(C(13)H(9)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment by two N atoms from two acridine ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254321/ https://www.ncbi.nlm.nih.gov/pubmed/22259353 http://dx.doi.org/10.1107/S1600536811053335 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [PdCl(2)(C(13)H(9)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment by two N atoms from two acridine ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex and the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and the acridine ligand is 84.66 (6)°. In the crystal, the complex molecules are stacked in columns along the a axis connected by C—H⋯Cl hydrogen bonds, forming chains along [110]. In the columns, numerous intermolecular π–π interactions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.722 (4) Å. |
format | Online Article Text |
id | pubmed-3254321 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543212012-01-18 trans-Bis(acridine-κN)dichloridopalladium(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [PdCl(2)(C(13)H(9)N)(2)], the Pd(II) ion is four-coordinated in an essentially square-planar environment by two N atoms from two acridine ligands and two Cl(−) anions. The Pd atom is located on an inversion centre, and thus the asymmetric unit contains one half of the complex and the PdN(2)Cl(2) unit is exactly planar. The dihedral angle between the PdN(2)Cl(2) unit and the acridine ligand is 84.66 (6)°. In the crystal, the complex molecules are stacked in columns along the a axis connected by C—H⋯Cl hydrogen bonds, forming chains along [110]. In the columns, numerous intermolecular π–π interactions between the six-membered rings are present, the shortest ring centroid–centroid distance being 3.722 (4) Å. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254321/ /pubmed/22259353 http://dx.doi.org/10.1107/S1600536811053335 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang trans-Bis(acridine-κN)dichloridopalladium(II) |
title |
trans-Bis(acridine-κN)dichloridopalladium(II) |
title_full |
trans-Bis(acridine-κN)dichloridopalladium(II) |
title_fullStr |
trans-Bis(acridine-κN)dichloridopalladium(II) |
title_full_unstemmed |
trans-Bis(acridine-κN)dichloridopalladium(II) |
title_short |
trans-Bis(acridine-κN)dichloridopalladium(II) |
title_sort | trans-bis(acridine-κn)dichloridopalladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254321/ https://www.ncbi.nlm.nih.gov/pubmed/22259353 http://dx.doi.org/10.1107/S1600536811053335 |
work_keys_str_mv | AT hakwang transbisacridinekndichloridopalladiumii |