Bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) S,S′)palladium(II)

In the title complex, (C(16)H(36)N)(2)[Pd(C(6)N(4)S(2))(2)], the centrosymmetric dianion is planar, with an r.m.s. deviation of 0.034 (8) Å. The Pd(II) atom, lying on an inversion center, has a square-planar coordination geometry, with Pd—S bond lengths of 2.276 (3) and 2.294 (3) Å.

Detalles Bibliográficos
Autores principales: Tomura, Masaaki, Yamashita, Yoshiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254323/
https://www.ncbi.nlm.nih.gov/pubmed/22259355
http://dx.doi.org/10.1107/S1600536811053402
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author Tomura, Masaaki
Yamashita, Yoshiro
author_facet Tomura, Masaaki
Yamashita, Yoshiro
author_sort Tomura, Masaaki
collection PubMed
description In the title complex, (C(16)H(36)N)(2)[Pd(C(6)N(4)S(2))(2)], the centrosymmetric dianion is planar, with an r.m.s. deviation of 0.034 (8) Å. The Pd(II) atom, lying on an inversion center, has a square-planar coordination geometry, with Pd—S bond lengths of 2.276 (3) and 2.294 (3) Å.
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spelling pubmed-32543232012-01-18 Bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) S,S′)palladium(II) Tomura, Masaaki Yamashita, Yoshiro Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, (C(16)H(36)N)(2)[Pd(C(6)N(4)S(2))(2)], the centrosymmetric dianion is planar, with an r.m.s. deviation of 0.034 (8) Å. The Pd(II) atom, lying on an inversion center, has a square-planar coordination geometry, with Pd—S bond lengths of 2.276 (3) and 2.294 (3) Å. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254323/ /pubmed/22259355 http://dx.doi.org/10.1107/S1600536811053402 Text en © Tomura and Yamashita 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tomura, Masaaki
Yamashita, Yoshiro
Bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) S,S′)palladium(II)
title Bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) S,S′)palladium(II)
title_full Bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) S,S′)palladium(II)
title_fullStr Bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) S,S′)palladium(II)
title_full_unstemmed Bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) S,S′)palladium(II)
title_short Bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) S,S′)palladium(II)
title_sort bis(tetra-n-butyl­ammonium) bis­(5,6-dicyano­pyrazine-2,3-dithiol­ato-κ(2) s,s′)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254323/
https://www.ncbi.nlm.nih.gov/pubmed/22259355
http://dx.doi.org/10.1107/S1600536811053402
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