Bis(O-ethyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-3-carbonitrile-κN (1))nickel(II)

The Ni(2+) ion in the title complex, [Ni(C(3)H(5)OS(2))(2)(C(6)H(4)N(2))(2)], is in a strongly distorted octa­hedral coordination environment formed by an N(2)S(4) donor set, with the Ni(2+) ion located on a centre of inversion. In the crystal, weak C—H⋯S and C—H⋯N inter­actions are observed....

Descripción completa

Detalles Bibliográficos
Autores principales: Kapoor, Sanjay, Kour, Ramandeep, Sachar, Renu, Kant, Rajni, Gupta, Vivek K., Kapoor, Kamini
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254324/
https://www.ncbi.nlm.nih.gov/pubmed/22259356
http://dx.doi.org/10.1107/S1600536811053475
_version_ 1782220833651949568
author Kapoor, Sanjay
Kour, Ramandeep
Sachar, Renu
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
author_facet Kapoor, Sanjay
Kour, Ramandeep
Sachar, Renu
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
author_sort Kapoor, Sanjay
collection PubMed
description The Ni(2+) ion in the title complex, [Ni(C(3)H(5)OS(2))(2)(C(6)H(4)N(2))(2)], is in a strongly distorted octa­hedral coordination environment formed by an N(2)S(4) donor set, with the Ni(2+) ion located on a centre of inversion. In the crystal, weak C—H⋯S and C—H⋯N inter­actions are observed.
format Online
Article
Text
id pubmed-3254324
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32543242012-01-18 Bis(O-ethyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-3-carbonitrile-κN (1))nickel(II) Kapoor, Sanjay Kour, Ramandeep Sachar, Renu Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni(2+) ion in the title complex, [Ni(C(3)H(5)OS(2))(2)(C(6)H(4)N(2))(2)], is in a strongly distorted octa­hedral coordination environment formed by an N(2)S(4) donor set, with the Ni(2+) ion located on a centre of inversion. In the crystal, weak C—H⋯S and C—H⋯N inter­actions are observed. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254324/ /pubmed/22259356 http://dx.doi.org/10.1107/S1600536811053475 Text en © Kapoor et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kapoor, Sanjay
Kour, Ramandeep
Sachar, Renu
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Bis(O-ethyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-3-carbonitrile-κN (1))nickel(II)
title Bis(O-ethyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-3-carbonitrile-κN (1))nickel(II)
title_full Bis(O-ethyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-3-carbonitrile-κN (1))nickel(II)
title_fullStr Bis(O-ethyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-3-carbonitrile-κN (1))nickel(II)
title_full_unstemmed Bis(O-ethyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-3-carbonitrile-κN (1))nickel(II)
title_short Bis(O-ethyl dithio­carbonato-κ(2) S,S′)bis­(pyridine-3-carbonitrile-κN (1))nickel(II)
title_sort bis(o-ethyl dithio­carbonato-κ(2) s,s′)bis­(pyridine-3-carbonitrile-κn (1))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254324/
https://www.ncbi.nlm.nih.gov/pubmed/22259356
http://dx.doi.org/10.1107/S1600536811053475
work_keys_str_mv AT kapoorsanjay bisoethyldithiocarbonatok2ssbispyridine3carbonitrilekn1nickelii
AT kourramandeep bisoethyldithiocarbonatok2ssbispyridine3carbonitrilekn1nickelii
AT sacharrenu bisoethyldithiocarbonatok2ssbispyridine3carbonitrilekn1nickelii
AT kantrajni bisoethyldithiocarbonatok2ssbispyridine3carbonitrilekn1nickelii
AT guptavivekk bisoethyldithiocarbonatok2ssbispyridine3carbonitrilekn1nickelii
AT kapoorkamini bisoethyldithiocarbonatok2ssbispyridine3carbonitrilekn1nickelii

Ejemplares similares