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Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate
In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·0.5CH(3)CN, the Co(III) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolate dianion, and is further coordinated by a cyanide anion and a water molecule in the axial sites, completin...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254326/ https://www.ncbi.nlm.nih.gov/pubmed/22259359 http://dx.doi.org/10.1107/S160053681105330X |
Sumario: | In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·0.5CH(3)CN, the Co(III) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolate dianion, and is further coordinated by a cyanide anion and a water molecule in the axial sites, completing a distorted octahedral coordination geometry. In the crystal, pairs of bifurcated O—H⋯(O,O) hydrogen bonds link adjacent molecules, forming centrosymmetric dimers. The acetonitrile solvent molecule shows 0.5 occupancy. |
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