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Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate
In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·0.5CH(3)CN, the Co(III) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolate dianion, and is further coordinated by a cyanide anion and a water molecule in the axial sites, completin...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254326/ https://www.ncbi.nlm.nih.gov/pubmed/22259359 http://dx.doi.org/10.1107/S160053681105330X |
| _version_ | 1782220834097594368 |
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| author | Lin, Yang Hou, Guang-Feng Li, Guang-Ming Yan, Peng-Fei |
| author_facet | Lin, Yang Hou, Guang-Feng Li, Guang-Ming Yan, Peng-Fei |
| author_sort | Lin, Yang |
| collection | PubMed |
| description | In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·0.5CH(3)CN, the Co(III) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolate dianion, and is further coordinated by a cyanide anion and a water molecule in the axial sites, completing a distorted octahedral coordination geometry. In the crystal, pairs of bifurcated O—H⋯(O,O) hydrogen bonds link adjacent molecules, forming centrosymmetric dimers. The acetonitrile solvent molecule shows 0.5 occupancy. |
| format | Online Article Text |
| id | pubmed-3254326 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32543262012-01-18 Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate Lin, Yang Hou, Guang-Feng Li, Guang-Ming Yan, Peng-Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(22)H(18)N(2)O(4))(CN)(H(2)O)]·0.5CH(3)CN, the Co(III) cation is N,N′,O,O′-chelated by a 6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolate dianion, and is further coordinated by a cyanide anion and a water molecule in the axial sites, completing a distorted octahedral coordination geometry. In the crystal, pairs of bifurcated O—H⋯(O,O) hydrogen bonds link adjacent molecules, forming centrosymmetric dimers. The acetonitrile solvent molecule shows 0.5 occupancy. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254326/ /pubmed/22259359 http://dx.doi.org/10.1107/S160053681105330X Text en © Lin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lin, Yang Hou, Guang-Feng Li, Guang-Ming Yan, Peng-Fei Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate |
| title | Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate |
| title_full | Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate |
| title_fullStr | Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate |
| title_full_unstemmed | Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate |
| title_short | Aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(III) acetonitrile hemisolvate |
| title_sort | aquacyanido{6,6′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethanylylidene)]diphenolato}cobalt(iii) acetonitrile hemisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254326/ https://www.ncbi.nlm.nih.gov/pubmed/22259359 http://dx.doi.org/10.1107/S160053681105330X |
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