(N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)

The title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NS(2))], has two independent mol­ecules in the asymmetric unit and each features a tetra­hedrally coordinated Sn(IV) atom as the dithio­carbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn at...

Descripción completa

Detalles Bibliográficos
Autores principales: Kamaludin, Nurul Farahana, Baba, Ibrahim, Awang, Normah, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254327/
https://www.ncbi.nlm.nih.gov/pubmed/22259360
http://dx.doi.org/10.1107/S1600536811053591
Descripción
Sumario:The title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NS(2))], has two independent mol­ecules in the asymmetric unit and each features a tetra­hedrally coordinated Sn(IV) atom as the dithio­carbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Sn⋯S(thione) = 3.1477 (6) and 2.9970 (5) Å for the independent mol­ecules], distortions from the ideal geometry are evident [the widest angle being 120.48 (5)°]. The most notable feature of the crystal packing is the formation of C—H⋯π inter­actions that lead to the formation of supra­molecular layers parallel to ([Image: see text]2[Image: see text]).

Ejemplares similares