(N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)

The title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NS(2))], has two independent mol­ecules in the asymmetric unit and each features a tetra­hedrally coordinated Sn(IV) atom as the dithio­carbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn at...

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Detalles Bibliográficos
Autores principales: Kamaludin, Nurul Farahana, Baba, Ibrahim, Awang, Normah, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254327/
https://www.ncbi.nlm.nih.gov/pubmed/22259360
http://dx.doi.org/10.1107/S1600536811053591
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author Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_facet Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Kamaludin, Nurul Farahana
collection PubMed
description The title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NS(2))], has two independent mol­ecules in the asymmetric unit and each features a tetra­hedrally coordinated Sn(IV) atom as the dithio­carbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Sn⋯S(thione) = 3.1477 (6) and 2.9970 (5) Å for the independent mol­ecules], distortions from the ideal geometry are evident [the widest angle being 120.48 (5)°]. The most notable feature of the crystal packing is the formation of C—H⋯π inter­actions that lead to the formation of supra­molecular layers parallel to ([Image: see text]2[Image: see text]).
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spelling pubmed-32543272012-01-18 (N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV) Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NS(2))], has two independent mol­ecules in the asymmetric unit and each features a tetra­hedrally coordinated Sn(IV) atom as the dithio­carbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Sn⋯S(thione) = 3.1477 (6) and 2.9970 (5) Å for the independent mol­ecules], distortions from the ideal geometry are evident [the widest angle being 120.48 (5)°]. The most notable feature of the crystal packing is the formation of C—H⋯π inter­actions that lead to the formation of supra­molecular layers parallel to ([Image: see text]2[Image: see text]). International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254327/ /pubmed/22259360 http://dx.doi.org/10.1107/S1600536811053591 Text en © Kamaludin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
(N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title (N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_full (N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_fullStr (N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_full_unstemmed (N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_short (N-Ethyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_sort (n-ethyl-n-phenyl­dithio­carbamato-κs)triphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254327/
https://www.ncbi.nlm.nih.gov/pubmed/22259360
http://dx.doi.org/10.1107/S1600536811053591
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