Tris(ethyl­enediamine-κ(2) N,N′)cobalt(III) aqua­tris­(oxalato-κ(2) O (1),O (2))indate(III)

In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(3)(H(2)O)], the Co(III) atom is coordinated by six N atoms from three ethyl­enediamine mol­ecules. The Co(III)—N bond lengths lie in the range 1.956 (4)–1.986 (4) Å. In the anion, the In(III) atom is seven-coordinated by six O a...

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Detalles Bibliográficos
Autores principales: Zhang, Zhe, Wang, Fuxiang, Liao, Shuangquan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254329/
https://www.ncbi.nlm.nih.gov/pubmed/22259362
http://dx.doi.org/10.1107/S1600536811053736
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author Zhang, Zhe
Wang, Fuxiang
Liao, Shuangquan
author_facet Zhang, Zhe
Wang, Fuxiang
Liao, Shuangquan
author_sort Zhang, Zhe
collection PubMed
description In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(3)(H(2)O)], the Co(III) atom is coordinated by six N atoms from three ethyl­enediamine mol­ecules. The Co(III)—N bond lengths lie in the range 1.956 (4)–1.986 (4) Å. In the anion, the In(III) atom is seven-coordinated by six O atoms from three oxalate ligands and by a water mol­ecule. The cations and anions are linked by extensive O—H⋯O and N—H⋯O hydrogen bonds, forming a supermolecular network.
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spelling pubmed-32543292012-01-18 Tris(ethyl­enediamine-κ(2) N,N′)cobalt(III) aqua­tris­(oxalato-κ(2) O (1),O (2))indate(III) Zhang, Zhe Wang, Fuxiang Liao, Shuangquan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(3)(H(2)O)], the Co(III) atom is coordinated by six N atoms from three ethyl­enediamine mol­ecules. The Co(III)—N bond lengths lie in the range 1.956 (4)–1.986 (4) Å. In the anion, the In(III) atom is seven-coordinated by six O atoms from three oxalate ligands and by a water mol­ecule. The cations and anions are linked by extensive O—H⋯O and N—H⋯O hydrogen bonds, forming a supermolecular network. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254329/ /pubmed/22259362 http://dx.doi.org/10.1107/S1600536811053736 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Zhe
Wang, Fuxiang
Liao, Shuangquan
Tris(ethyl­enediamine-κ(2) N,N′)cobalt(III) aqua­tris­(oxalato-κ(2) O (1),O (2))indate(III)
title Tris(ethyl­enediamine-κ(2) N,N′)cobalt(III) aqua­tris­(oxalato-κ(2) O (1),O (2))indate(III)
title_full Tris(ethyl­enediamine-κ(2) N,N′)cobalt(III) aqua­tris­(oxalato-κ(2) O (1),O (2))indate(III)
title_fullStr Tris(ethyl­enediamine-κ(2) N,N′)cobalt(III) aqua­tris­(oxalato-κ(2) O (1),O (2))indate(III)
title_full_unstemmed Tris(ethyl­enediamine-κ(2) N,N′)cobalt(III) aqua­tris­(oxalato-κ(2) O (1),O (2))indate(III)
title_short Tris(ethyl­enediamine-κ(2) N,N′)cobalt(III) aqua­tris­(oxalato-κ(2) O (1),O (2))indate(III)
title_sort tris(ethyl­enediamine-κ(2) n,n′)cobalt(iii) aqua­tris­(oxalato-κ(2) o (1),o (2))indate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254329/
https://www.ncbi.nlm.nih.gov/pubmed/22259362
http://dx.doi.org/10.1107/S1600536811053736
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AT wangfuxiang trisethylenediaminek2nncobaltiiiaquatrisoxalatok2o1o2indateiii
AT liaoshuangquan trisethylenediaminek2nncobaltiiiaquatrisoxalatok2o1o2indateiii

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