cis-Bis(acetonitrile-κN)bis­(2,2′-bipyridine-κ(2) N,N′)ruthenium(II) tetra­fluoridoborate

In the cation of the title compound, [Ru(CH(3)CN)(2)(C(10)H(8)N(2))(2)](BF(4))(2), the Ru(II) atom is six-coordinated in a distorted octa­hedral geometry by the N atoms of the two 2,2′-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol­ecules. The dihedral angles formed by the pyridine r...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Xu, Feng, Huang, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254331/
https://www.ncbi.nlm.nih.gov/pubmed/22259364
http://dx.doi.org/10.1107/S1600536811053864
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author Wang, Ying
Xu, Feng
Huang, Wei
author_facet Wang, Ying
Xu, Feng
Huang, Wei
author_sort Wang, Ying
collection PubMed
description In the cation of the title compound, [Ru(CH(3)CN)(2)(C(10)H(8)N(2))(2)](BF(4))(2), the Ru(II) atom is six-coordinated in a distorted octa­hedral geometry by the N atoms of the two 2,2′-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol­ecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86 (12) and 10.12 (14)°. In the crystal, the cations and anions are linked by C—H⋯F hydrogen bonds into a three-dimensional network.
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spelling pubmed-32543312012-01-18 cis-Bis(acetonitrile-κN)bis­(2,2′-bipyridine-κ(2) N,N′)ruthenium(II) tetra­fluoridoborate Wang, Ying Xu, Feng Huang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Ru(CH(3)CN)(2)(C(10)H(8)N(2))(2)](BF(4))(2), the Ru(II) atom is six-coordinated in a distorted octa­hedral geometry by the N atoms of the two 2,2′-bipyridine (bpy) ligands and two cis-arranged acetonitrile mol­ecules. The dihedral angles formed by the pyridine rings of the bpy ligands are 8.86 (12) and 10.12 (14)°. In the crystal, the cations and anions are linked by C—H⋯F hydrogen bonds into a three-dimensional network. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254331/ /pubmed/22259364 http://dx.doi.org/10.1107/S1600536811053864 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ying
Xu, Feng
Huang, Wei
cis-Bis(acetonitrile-κN)bis­(2,2′-bipyridine-κ(2) N,N′)ruthenium(II) tetra­fluoridoborate
title cis-Bis(acetonitrile-κN)bis­(2,2′-bipyridine-κ(2) N,N′)ruthenium(II) tetra­fluoridoborate
title_full cis-Bis(acetonitrile-κN)bis­(2,2′-bipyridine-κ(2) N,N′)ruthenium(II) tetra­fluoridoborate
title_fullStr cis-Bis(acetonitrile-κN)bis­(2,2′-bipyridine-κ(2) N,N′)ruthenium(II) tetra­fluoridoborate
title_full_unstemmed cis-Bis(acetonitrile-κN)bis­(2,2′-bipyridine-κ(2) N,N′)ruthenium(II) tetra­fluoridoborate
title_short cis-Bis(acetonitrile-κN)bis­(2,2′-bipyridine-κ(2) N,N′)ruthenium(II) tetra­fluoridoborate
title_sort cis-bis(acetonitrile-κn)bis­(2,2′-bipyridine-κ(2) n,n′)ruthenium(ii) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254331/
https://www.ncbi.nlm.nih.gov/pubmed/22259364
http://dx.doi.org/10.1107/S1600536811053864
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