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Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate

In the title compound, [Co(C(5)H(4)NO(3))(2)(H(2)O)(2)]·2H(2)O, the coordination polyhedron around the six-coordinate Co(II) ion is formed by two equatorial 5-methyl­isoxazole-3-carboxyl­ate ligands in an N,O (3)-bidentate fashion through the isoxazole N atom and a carboxyl­ate O atom, and by two ax...

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Detalles Bibliográficos
Autores principales: Wang, Yan, Zhao, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254332/
https://www.ncbi.nlm.nih.gov/pubmed/22259365
http://dx.doi.org/10.1107/S1600536811053414
Descripción
Sumario:In the title compound, [Co(C(5)H(4)NO(3))(2)(H(2)O)(2)]·2H(2)O, the coordination polyhedron around the six-coordinate Co(II) ion is formed by two equatorial 5-methyl­isoxazole-3-carboxyl­ate ligands in an N,O (3)-bidentate fashion through the isoxazole N atom and a carboxyl­ate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water mol­ecule (the full comlex being completed by application of inversion). In the crystal, the water mol­ecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water mol­ecule and the carboxyl­ate groups.