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Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2) N,O (3))cobalt(II) dihydrate
In the title compound, [Co(C(5)H(4)NO(3))(2)(H(2)O)(2)]·2H(2)O, the coordination polyhedron around the six-coordinate Co(II) ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O (3)-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two ax...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254332/ https://www.ncbi.nlm.nih.gov/pubmed/22259365 http://dx.doi.org/10.1107/S1600536811053414 |
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author | Wang, Yan Zhao, Jing |
author_facet | Wang, Yan Zhao, Jing |
author_sort | Wang, Yan |
collection | PubMed |
description | In the title compound, [Co(C(5)H(4)NO(3))(2)(H(2)O)(2)]·2H(2)O, the coordination polyhedron around the six-coordinate Co(II) ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O (3)-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water molecule (the full comlex being completed by application of inversion). In the crystal, the water molecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water molecule and the carboxylate groups. |
format | Online Article Text |
id | pubmed-3254332 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543322012-01-18 Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2) N,O (3))cobalt(II) dihydrate Wang, Yan Zhao, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(5)H(4)NO(3))(2)(H(2)O)(2)]·2H(2)O, the coordination polyhedron around the six-coordinate Co(II) ion is formed by two equatorial 5-methylisoxazole-3-carboxylate ligands in an N,O (3)-bidentate fashion through the isoxazole N atom and a carboxylate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water molecule (the full comlex being completed by application of inversion). In the crystal, the water molecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water molecule and the carboxylate groups. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254332/ /pubmed/22259365 http://dx.doi.org/10.1107/S1600536811053414 Text en © Wang and Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Yan Zhao, Jing Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2) N,O (3))cobalt(II) dihydrate |
title | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2)
N,O
(3))cobalt(II) dihydrate |
title_full | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2)
N,O
(3))cobalt(II) dihydrate |
title_fullStr | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2)
N,O
(3))cobalt(II) dihydrate |
title_full_unstemmed | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2)
N,O
(3))cobalt(II) dihydrate |
title_short | Diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2)
N,O
(3))cobalt(II) dihydrate |
title_sort | diaquabis(5-methyl-1,2-oxazole-3-carboxylato-κ(2)
n,o
(3))cobalt(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254332/ https://www.ncbi.nlm.nih.gov/pubmed/22259365 http://dx.doi.org/10.1107/S1600536811053414 |
work_keys_str_mv | AT wangyan diaquabis5methyl12oxazole3carboxylatok2no3cobaltiidihydrate AT zhaojing diaquabis5methyl12oxazole3carboxylatok2no3cobaltiidihydrate |