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Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate

In the title compound, [Co(C(5)H(4)NO(3))(2)(H(2)O)(2)]·2H(2)O, the coordination polyhedron around the six-coordinate Co(II) ion is formed by two equatorial 5-methyl­isoxazole-3-carboxyl­ate ligands in an N,O (3)-bidentate fashion through the isoxazole N atom and a carboxyl­ate O atom, and by two ax...

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Detalles Bibliográficos
Autores principales: Wang, Yan, Zhao, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254332/
https://www.ncbi.nlm.nih.gov/pubmed/22259365
http://dx.doi.org/10.1107/S1600536811053414
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author Wang, Yan
Zhao, Jing
author_facet Wang, Yan
Zhao, Jing
author_sort Wang, Yan
collection PubMed
description In the title compound, [Co(C(5)H(4)NO(3))(2)(H(2)O)(2)]·2H(2)O, the coordination polyhedron around the six-coordinate Co(II) ion is formed by two equatorial 5-methyl­isoxazole-3-carboxyl­ate ligands in an N,O (3)-bidentate fashion through the isoxazole N atom and a carboxyl­ate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water mol­ecule (the full comlex being completed by application of inversion). In the crystal, the water mol­ecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water mol­ecule and the carboxyl­ate groups.
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spelling pubmed-32543322012-01-18 Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate Wang, Yan Zhao, Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(5)H(4)NO(3))(2)(H(2)O)(2)]·2H(2)O, the coordination polyhedron around the six-coordinate Co(II) ion is formed by two equatorial 5-methyl­isoxazole-3-carboxyl­ate ligands in an N,O (3)-bidentate fashion through the isoxazole N atom and a carboxyl­ate O atom, and by two axial water ligands. The asymmetric unit consists of half of the complex and one water mol­ecule (the full comlex being completed by application of inversion). In the crystal, the water mol­ecules participate in the formation of an intricate three-dimensional network of hydrogen bonds involving the coordinated water mol­ecule and the carboxyl­ate groups. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254332/ /pubmed/22259365 http://dx.doi.org/10.1107/S1600536811053414 Text en © Wang and Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yan
Zhao, Jing
Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate
title Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate
title_full Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate
title_fullStr Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate
title_full_unstemmed Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate
title_short Diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) N,O (3))cobalt(II) dihydrate
title_sort diaqua­bis­(5-methyl-1,2-oxazole-3-car­box­yl­ato-κ(2) n,o (3))cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254332/
https://www.ncbi.nlm.nih.gov/pubmed/22259365
http://dx.doi.org/10.1107/S1600536811053414
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