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Bis(1,1-dimethylguanidinium) tetraaquadimethyltin(IV) bis(sulfate)
Single crystals of the title salt, (C(3)H(10)N(3))(2)[Sn(CH(3))(2)(H(2)O)(4)](SO(4))(2), formed concomitantly with the already known [Sn(CH(3))(3)](2)SO(4)·2H(2)O. In the title structure, the Sn(IV) atom displays a slightly distorted octahedral coordination geometry defined by four O water atoms in...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254333/ https://www.ncbi.nlm.nih.gov/pubmed/22259366 http://dx.doi.org/10.1107/S1600536811053761 |
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author | Boye, Mouhamadou Sembene Diasse-Sarr, Aminata Lebraud, Eric Guionneau, Philippe |
author_facet | Boye, Mouhamadou Sembene Diasse-Sarr, Aminata Lebraud, Eric Guionneau, Philippe |
author_sort | Boye, Mouhamadou Sembene |
collection | PubMed |
description | Single crystals of the title salt, (C(3)H(10)N(3))(2)[Sn(CH(3))(2)(H(2)O)(4)](SO(4))(2), formed concomitantly with the already known [Sn(CH(3))(3)](2)SO(4)·2H(2)O. In the title structure, the Sn(IV) atom displays a slightly distorted octahedral coordination geometry defined by four O water atoms in the equatorial positions and two methyl groups in the axial positions. In the crystal, various O—H⋯O and N—H⋯O hydrogen-bonding interactions between the organic cation and the coordinated water molecules as donors and the sulfate O atoms as acceptors result in a three-dimensional structure. The Sn(IV) atom is located on an inversion centre, resulting in half of the complex metal cation being in the asymmetric unit. |
format | Online Article Text |
id | pubmed-3254333 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543332012-01-18 Bis(1,1-dimethylguanidinium) tetraaquadimethyltin(IV) bis(sulfate) Boye, Mouhamadou Sembene Diasse-Sarr, Aminata Lebraud, Eric Guionneau, Philippe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Single crystals of the title salt, (C(3)H(10)N(3))(2)[Sn(CH(3))(2)(H(2)O)(4)](SO(4))(2), formed concomitantly with the already known [Sn(CH(3))(3)](2)SO(4)·2H(2)O. In the title structure, the Sn(IV) atom displays a slightly distorted octahedral coordination geometry defined by four O water atoms in the equatorial positions and two methyl groups in the axial positions. In the crystal, various O—H⋯O and N—H⋯O hydrogen-bonding interactions between the organic cation and the coordinated water molecules as donors and the sulfate O atoms as acceptors result in a three-dimensional structure. The Sn(IV) atom is located on an inversion centre, resulting in half of the complex metal cation being in the asymmetric unit. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254333/ /pubmed/22259366 http://dx.doi.org/10.1107/S1600536811053761 Text en © Boye et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Boye, Mouhamadou Sembene Diasse-Sarr, Aminata Lebraud, Eric Guionneau, Philippe Bis(1,1-dimethylguanidinium) tetraaquadimethyltin(IV) bis(sulfate) |
title | Bis(1,1-dimethylguanidinium) tetraaquadimethyltin(IV) bis(sulfate) |
title_full | Bis(1,1-dimethylguanidinium) tetraaquadimethyltin(IV) bis(sulfate) |
title_fullStr | Bis(1,1-dimethylguanidinium) tetraaquadimethyltin(IV) bis(sulfate) |
title_full_unstemmed | Bis(1,1-dimethylguanidinium) tetraaquadimethyltin(IV) bis(sulfate) |
title_short | Bis(1,1-dimethylguanidinium) tetraaquadimethyltin(IV) bis(sulfate) |
title_sort | bis(1,1-dimethylguanidinium) tetraaquadimethyltin(iv) bis(sulfate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254333/ https://www.ncbi.nlm.nih.gov/pubmed/22259366 http://dx.doi.org/10.1107/S1600536811053761 |
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