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Tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(II) dihydrate

In the title compound, K(3)[Cu(C(10)H(12)N(2)O(10)P)]·2H(2)O, the Cu(II) ion, one potassium cation and a P atom are situated on a twofold rotation axis. The Cu(II) ion is coordinated by two N and four O atoms from one bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinate ligand in a distorted oc...

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Detalles Bibliográficos
Autores principales: Liu, Liyan, Zhang, Rui, Fan, Ping, Yu, Zhan, Zhang, Xiangdong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254335/
https://www.ncbi.nlm.nih.gov/pubmed/22259368
http://dx.doi.org/10.1107/S1600536811053608
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author Liu, Liyan
Zhang, Rui
Fan, Ping
Yu, Zhan
Zhang, Xiangdong
author_facet Liu, Liyan
Zhang, Rui
Fan, Ping
Yu, Zhan
Zhang, Xiangdong
author_sort Liu, Liyan
collection PubMed
description In the title compound, K(3)[Cu(C(10)H(12)N(2)O(10)P)]·2H(2)O, the Cu(II) ion, one potassium cation and a P atom are situated on a twofold rotation axis. The Cu(II) ion is coordinated by two N and four O atoms from one bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinate ligand in a distorted octa­hedral coordination geometry. The two crystallographically independent potassium ions exhibit different coordination environments. The potassium ion in a general position is hepta­coordinated by five carboxyl­ate O atoms, one phosphinate O atom and one water mol­ecule [K—O = 2.718 (3)–3.040 (3) Å], and the potassium ion situated on the twofold rotation axis is hexa­coordinated by four carboxyl­ate O atoms and two water mol­ecules [K—O = 2.618 (3)–2.771 (3) Å]. The water mol­ecules are also involved in formation of inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-32543352012-01-18 Tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(II) dihydrate Liu, Liyan Zhang, Rui Fan, Ping Yu, Zhan Zhang, Xiangdong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, K(3)[Cu(C(10)H(12)N(2)O(10)P)]·2H(2)O, the Cu(II) ion, one potassium cation and a P atom are situated on a twofold rotation axis. The Cu(II) ion is coordinated by two N and four O atoms from one bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinate ligand in a distorted octa­hedral coordination geometry. The two crystallographically independent potassium ions exhibit different coordination environments. The potassium ion in a general position is hepta­coordinated by five carboxyl­ate O atoms, one phosphinate O atom and one water mol­ecule [K—O = 2.718 (3)–3.040 (3) Å], and the potassium ion situated on the twofold rotation axis is hexa­coordinated by four carboxyl­ate O atoms and two water mol­ecules [K—O = 2.618 (3)–2.771 (3) Å]. The water mol­ecules are also involved in formation of inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254335/ /pubmed/22259368 http://dx.doi.org/10.1107/S1600536811053608 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Liyan
Zhang, Rui
Fan, Ping
Yu, Zhan
Zhang, Xiangdong
Tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(II) dihydrate
title Tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(II) dihydrate
title_full Tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(II) dihydrate
title_fullStr Tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(II) dihydrate
title_full_unstemmed Tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(II) dihydrate
title_short Tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(II) dihydrate
title_sort tripotassium (bis­{[bis­(carboxyl­atometh­yl)amino]­meth­yl}phosphinato)cuprate(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254335/
https://www.ncbi.nlm.nih.gov/pubmed/22259368
http://dx.doi.org/10.1107/S1600536811053608
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AT fanping tripotassiumbisbiscarboxylatomethylaminomethylphosphinatocuprateiidihydrate
AT yuzhan tripotassiumbisbiscarboxylatomethylaminomethylphosphinatocuprateiidihydrate
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