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Tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(II) dihydrate
In the title compound, K(3)[Cu(C(10)H(12)N(2)O(10)P)]·2H(2)O, the Cu(II) ion, one potassium cation and a P atom are situated on a twofold rotation axis. The Cu(II) ion is coordinated by two N and four O atoms from one bis{[bis(carboxylatomethyl)amino]methyl}phosphinate ligand in a distorted oc...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254335/ https://www.ncbi.nlm.nih.gov/pubmed/22259368 http://dx.doi.org/10.1107/S1600536811053608 |
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author | Liu, Liyan Zhang, Rui Fan, Ping Yu, Zhan Zhang, Xiangdong |
author_facet | Liu, Liyan Zhang, Rui Fan, Ping Yu, Zhan Zhang, Xiangdong |
author_sort | Liu, Liyan |
collection | PubMed |
description | In the title compound, K(3)[Cu(C(10)H(12)N(2)O(10)P)]·2H(2)O, the Cu(II) ion, one potassium cation and a P atom are situated on a twofold rotation axis. The Cu(II) ion is coordinated by two N and four O atoms from one bis{[bis(carboxylatomethyl)amino]methyl}phosphinate ligand in a distorted octahedral coordination geometry. The two crystallographically independent potassium ions exhibit different coordination environments. The potassium ion in a general position is heptacoordinated by five carboxylate O atoms, one phosphinate O atom and one water molecule [K—O = 2.718 (3)–3.040 (3) Å], and the potassium ion situated on the twofold rotation axis is hexacoordinated by four carboxylate O atoms and two water molecules [K—O = 2.618 (3)–2.771 (3) Å]. The water molecules are also involved in formation of intermolecular O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3254335 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543352012-01-18 Tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(II) dihydrate Liu, Liyan Zhang, Rui Fan, Ping Yu, Zhan Zhang, Xiangdong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, K(3)[Cu(C(10)H(12)N(2)O(10)P)]·2H(2)O, the Cu(II) ion, one potassium cation and a P atom are situated on a twofold rotation axis. The Cu(II) ion is coordinated by two N and four O atoms from one bis{[bis(carboxylatomethyl)amino]methyl}phosphinate ligand in a distorted octahedral coordination geometry. The two crystallographically independent potassium ions exhibit different coordination environments. The potassium ion in a general position is heptacoordinated by five carboxylate O atoms, one phosphinate O atom and one water molecule [K—O = 2.718 (3)–3.040 (3) Å], and the potassium ion situated on the twofold rotation axis is hexacoordinated by four carboxylate O atoms and two water molecules [K—O = 2.618 (3)–2.771 (3) Å]. The water molecules are also involved in formation of intermolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254335/ /pubmed/22259368 http://dx.doi.org/10.1107/S1600536811053608 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Liyan Zhang, Rui Fan, Ping Yu, Zhan Zhang, Xiangdong Tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(II) dihydrate |
title | Tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(II) dihydrate |
title_full | Tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(II) dihydrate |
title_fullStr | Tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(II) dihydrate |
title_full_unstemmed | Tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(II) dihydrate |
title_short | Tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(II) dihydrate |
title_sort | tripotassium (bis{[bis(carboxylatomethyl)amino]methyl}phosphinato)cuprate(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254335/ https://www.ncbi.nlm.nih.gov/pubmed/22259368 http://dx.doi.org/10.1107/S1600536811053608 |
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