Bis[6-(1H-benzimidazol-2-yl-κN (3))pyridine-2-carboxyl­ato-κ(2) N,O]cobalt(II) dihydrate

In the title compound, [Co(C(13)H(8)N(3)O(2))(2)]·2H(2)O, the Co(II) atom has a distorted octa­hedral environment defined by four N atoms and two O atoms from two 6-(1H-benzimidazol-2-yl)pyridine-2-carboxyl­ate ligands. In the crystal, the complex mol­ecules and uncoordinated water mol­ecules are li...

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Detalles Bibliográficos
Autores principales: Han, Liying, Sun, Dajun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254336/
https://www.ncbi.nlm.nih.gov/pubmed/22259369
http://dx.doi.org/10.1107/S1600536811053700
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author Han, Liying
Sun, Dajun
author_facet Han, Liying
Sun, Dajun
author_sort Han, Liying
collection PubMed
description In the title compound, [Co(C(13)H(8)N(3)O(2))(2)]·2H(2)O, the Co(II) atom has a distorted octa­hedral environment defined by four N atoms and two O atoms from two 6-(1H-benzimidazol-2-yl)pyridine-2-carboxyl­ate ligands. In the crystal, the complex mol­ecules and uncoordinated water mol­ecules are linked via N—H⋯O and O—H⋯O hydrogen bonds, forming a two-dimensional supra­molecular structure parallel to (010). π–π inter­actions are present between the imidazole, pyridine and benzene rings [centroid–centroid distances = 3.528 (2), 3.592 (2), 3.680 (2) and 3.732 (3) Å].
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spelling pubmed-32543362012-01-18 Bis[6-(1H-benzimidazol-2-yl-κN (3))pyridine-2-carboxyl­ato-κ(2) N,O]cobalt(II) dihydrate Han, Liying Sun, Dajun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(13)H(8)N(3)O(2))(2)]·2H(2)O, the Co(II) atom has a distorted octa­hedral environment defined by four N atoms and two O atoms from two 6-(1H-benzimidazol-2-yl)pyridine-2-carboxyl­ate ligands. In the crystal, the complex mol­ecules and uncoordinated water mol­ecules are linked via N—H⋯O and O—H⋯O hydrogen bonds, forming a two-dimensional supra­molecular structure parallel to (010). π–π inter­actions are present between the imidazole, pyridine and benzene rings [centroid–centroid distances = 3.528 (2), 3.592 (2), 3.680 (2) and 3.732 (3) Å]. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254336/ /pubmed/22259369 http://dx.doi.org/10.1107/S1600536811053700 Text en © Han and Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Liying
Sun, Dajun
Bis[6-(1H-benzimidazol-2-yl-κN (3))pyridine-2-carboxyl­ato-κ(2) N,O]cobalt(II) dihydrate
title Bis[6-(1H-benzimidazol-2-yl-κN (3))pyridine-2-carboxyl­ato-κ(2) N,O]cobalt(II) dihydrate
title_full Bis[6-(1H-benzimidazol-2-yl-κN (3))pyridine-2-carboxyl­ato-κ(2) N,O]cobalt(II) dihydrate
title_fullStr Bis[6-(1H-benzimidazol-2-yl-κN (3))pyridine-2-carboxyl­ato-κ(2) N,O]cobalt(II) dihydrate
title_full_unstemmed Bis[6-(1H-benzimidazol-2-yl-κN (3))pyridine-2-carboxyl­ato-κ(2) N,O]cobalt(II) dihydrate
title_short Bis[6-(1H-benzimidazol-2-yl-κN (3))pyridine-2-carboxyl­ato-κ(2) N,O]cobalt(II) dihydrate
title_sort bis[6-(1h-benzimidazol-2-yl-κn (3))pyridine-2-carboxyl­ato-κ(2) n,o]cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254336/
https://www.ncbi.nlm.nih.gov/pubmed/22259369
http://dx.doi.org/10.1107/S1600536811053700
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AT sundajun bis61hbenzimidazol2ylkn3pyridine2carboxylatok2nocobaltiidihydrate

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