catena-Poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2);N (4),O (3)] nitrate]

The crystal structure of the title compound, {[Zn(C(6)H(3)N(2)O(4))(H(2)O)(2)]NO(3)}(n), is built of zigzag cationic chains propagating in [010] with nitrate anions located in the space between the chains. The Zn(II) ion is coordinated by N and O atoms of two symmetry-related ligands in equatorial s...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254337/
https://www.ncbi.nlm.nih.gov/pubmed/22259370
http://dx.doi.org/10.1107/S1600536811054031
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description The crystal structure of the title compound, {[Zn(C(6)H(3)N(2)O(4))(H(2)O)(2)]NO(3)}(n), is built of zigzag cationic chains propagating in [010] with nitrate anions located in the space between the chains. The Zn(II) ion is coordinated by N and O atoms of two symmetry-related ligands in equatorial sites, and by two water O atoms at the axial sites of a distorted octa­hedron. One carboxyl­ate group of the ligand remains protonated, serving as a donor in a short intra­molecular O—H⋯O hydrogen bond. The coordinated water mol­ecules are donors and the nitrate O atoms act as acceptors in a network of O—H⋯O hydrogen bonds.
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spelling pubmed-32543372012-01-18 catena-Poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2);N (4),O (3)] nitrate] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, {[Zn(C(6)H(3)N(2)O(4))(H(2)O)(2)]NO(3)}(n), is built of zigzag cationic chains propagating in [010] with nitrate anions located in the space between the chains. The Zn(II) ion is coordinated by N and O atoms of two symmetry-related ligands in equatorial sites, and by two water O atoms at the axial sites of a distorted octa­hedron. One carboxyl­ate group of the ligand remains protonated, serving as a donor in a short intra­molecular O—H⋯O hydrogen bond. The coordinated water mol­ecules are donors and the nitrate O atoms act as acceptors in a network of O—H⋯O hydrogen bonds. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254337/ /pubmed/22259370 http://dx.doi.org/10.1107/S1600536811054031 Text en © Starosta and Leciejewicz 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
catena-Poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2);N (4),O (3)] nitrate]
title catena-Poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2);N (4),O (3)] nitrate]
title_full catena-Poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2);N (4),O (3)] nitrate]
title_fullStr catena-Poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2);N (4),O (3)] nitrate]
title_full_unstemmed catena-Poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2);N (4),O (3)] nitrate]
title_short catena-Poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) N (1),O (2);N (4),O (3)] nitrate]
title_sort catena-poly[[(diaqua­zinc)-μ-3-carb­oxy­pyrazine-2-carboxyl­ato-κ(4) n (1),o (2);n (4),o (3)] nitrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254337/
https://www.ncbi.nlm.nih.gov/pubmed/22259370
http://dx.doi.org/10.1107/S1600536811054031
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AT leciejewiczjanusz catenapolydiaquazincm3carboxypyrazine2carboxylatok4n1o2n4o3nitrate

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