Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) 2-hy­droxy-3,5-dinitro­benzoate

In the cation of the title salt, [Ag(C(12)H(6)N(2)O(2))(2)](C(7)H(3)N(2)O(7)), the Ag(I) atom is coordinated in a distorted tetra­hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro­salicylate anion has only a short contact [2.847 (6) Å] between one...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Shen-Tang, Che, Guang-Bo, Liu, Chun-Bo, Wang, Xing, Liu, Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254338/
https://www.ncbi.nlm.nih.gov/pubmed/22259371
http://dx.doi.org/10.1107/S1600536811053785
_version_ 1782220836815503360
author Wang, Shen-Tang
Che, Guang-Bo
Liu, Chun-Bo
Wang, Xing
Liu, Ling
author_facet Wang, Shen-Tang
Che, Guang-Bo
Liu, Chun-Bo
Wang, Xing
Liu, Ling
author_sort Wang, Shen-Tang
collection PubMed
description In the cation of the title salt, [Ag(C(12)H(6)N(2)O(2))(2)](C(7)H(3)N(2)O(7)), the Ag(I) atom is coordinated in a distorted tetra­hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro­salicylate anion has only a short contact [2.847 (6) Å] between one of its O atoms and the Ag(I) atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4 (1)°. There is an intra­molecular O—H⋯O hydrogen bond in the 3,5-dinitro­salicylate anion.
format Online
Article
Text
id pubmed-3254338
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32543382012-01-18 Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) 2-hy­droxy-3,5-dinitro­benzoate Wang, Shen-Tang Che, Guang-Bo Liu, Chun-Bo Wang, Xing Liu, Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title salt, [Ag(C(12)H(6)N(2)O(2))(2)](C(7)H(3)N(2)O(7)), the Ag(I) atom is coordinated in a distorted tetra­hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro­salicylate anion has only a short contact [2.847 (6) Å] between one of its O atoms and the Ag(I) atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4 (1)°. There is an intra­molecular O—H⋯O hydrogen bond in the 3,5-dinitro­salicylate anion. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254338/ /pubmed/22259371 http://dx.doi.org/10.1107/S1600536811053785 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Shen-Tang
Che, Guang-Bo
Liu, Chun-Bo
Wang, Xing
Liu, Ling
Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) 2-hy­droxy-3,5-dinitro­benzoate
title Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) 2-hy­droxy-3,5-dinitro­benzoate
title_full Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) 2-hy­droxy-3,5-dinitro­benzoate
title_fullStr Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) 2-hy­droxy-3,5-dinitro­benzoate
title_full_unstemmed Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) 2-hy­droxy-3,5-dinitro­benzoate
title_short Bis(1,10-phenanthroline-5,6-dione-κ(2) N,N′)silver(I) 2-hy­droxy-3,5-dinitro­benzoate
title_sort bis(1,10-phenanthroline-5,6-dione-κ(2) n,n′)silver(i) 2-hy­droxy-3,5-dinitro­benzoate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254338/
https://www.ncbi.nlm.nih.gov/pubmed/22259371
http://dx.doi.org/10.1107/S1600536811053785
work_keys_str_mv AT wangshentang bis110phenanthroline56dionek2nnsilveri2hydroxy35dinitrobenzoate
AT cheguangbo bis110phenanthroline56dionek2nnsilveri2hydroxy35dinitrobenzoate
AT liuchunbo bis110phenanthroline56dionek2nnsilveri2hydroxy35dinitrobenzoate
AT wangxing bis110phenanthroline56dionek2nnsilveri2hydroxy35dinitrobenzoate
AT liuling bis110phenanthroline56dionek2nnsilveri2hydroxy35dinitrobenzoate

Ejemplares similares