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(2,2′-Bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate

In the title compound, [RuCl(C(15)H(11)N(3))(C(12)H(8)N(2)O(4))]ClO(4)·C(2)H(5)OH·H(2)O, the geometry of the ClN(5) coordination set around the Ru(II) atom is close to octa­hedral, but distorted on account of the limited bite angles of the polypyridyl ligands. The complexes are linked by O—H⋯O hydro...

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Detalles Bibliográficos
Autores principales: Nielsen, Anne, McKenzie, Christine J., Bond, Andrew D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254339/
https://www.ncbi.nlm.nih.gov/pubmed/22259372
http://dx.doi.org/10.1107/S1600536811054195
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author Nielsen, Anne
McKenzie, Christine J.
Bond, Andrew D.
author_facet Nielsen, Anne
McKenzie, Christine J.
Bond, Andrew D.
author_sort Nielsen, Anne
collection PubMed
description In the title compound, [RuCl(C(15)H(11)N(3))(C(12)H(8)N(2)O(4))]ClO(4)·C(2)H(5)OH·H(2)O, the geometry of the ClN(5) coordination set around the Ru(II) atom is close to octa­hedral, but distorted on account of the limited bite angles of the polypyridyl ligands. The complexes are linked by O—H⋯O hydrogen bonds between the carboxyl groups and the crystal lattice water mol­ecules into chains along [110]. Face-to-face stacking inter­actions are formed between terpyridine ligands, with inter­planar separations of 3.66 (1) and 3.42 (1) Å, and between bipyridine-4,4′-dicarb­oxy­lic acid ligands, with inter­planar separations of 3.65 (1) and 3.72 (1) Å. Three O atoms of the perchlorate ion are each disordered equally over two positions. The hy­droxy group of the ethanol mol­ecule is also disordered over two sites with refined occupancies of 0.794 (9) and 0.206 (9).
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spelling pubmed-32543392012-01-18 (2,2′-Bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate Nielsen, Anne McKenzie, Christine J. Bond, Andrew D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(C(15)H(11)N(3))(C(12)H(8)N(2)O(4))]ClO(4)·C(2)H(5)OH·H(2)O, the geometry of the ClN(5) coordination set around the Ru(II) atom is close to octa­hedral, but distorted on account of the limited bite angles of the polypyridyl ligands. The complexes are linked by O—H⋯O hydrogen bonds between the carboxyl groups and the crystal lattice water mol­ecules into chains along [110]. Face-to-face stacking inter­actions are formed between terpyridine ligands, with inter­planar separations of 3.66 (1) and 3.42 (1) Å, and between bipyridine-4,4′-dicarb­oxy­lic acid ligands, with inter­planar separations of 3.65 (1) and 3.72 (1) Å. Three O atoms of the perchlorate ion are each disordered equally over two positions. The hy­droxy group of the ethanol mol­ecule is also disordered over two sites with refined occupancies of 0.794 (9) and 0.206 (9). International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254339/ /pubmed/22259372 http://dx.doi.org/10.1107/S1600536811054195 Text en © Nielsen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nielsen, Anne
McKenzie, Christine J.
Bond, Andrew D.
(2,2′-Bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate
title (2,2′-Bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate
title_full (2,2′-Bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate
title_fullStr (2,2′-Bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate
title_full_unstemmed (2,2′-Bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate
title_short (2,2′-Bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate
title_sort (2,2′-bipyridine-4,4′-dicarb­oxy­lic acid-κ(2) n,n′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) n,n′,n′′)ruthenium(ii) perchlorate ethanol monosolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254339/
https://www.ncbi.nlm.nih.gov/pubmed/22259372
http://dx.doi.org/10.1107/S1600536811054195
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