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(2,2′-Bipyridine-4,4′-dicarboxylic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate
In the title compound, [RuCl(C(15)H(11)N(3))(C(12)H(8)N(2)O(4))]ClO(4)·C(2)H(5)OH·H(2)O, the geometry of the ClN(5) coordination set around the Ru(II) atom is close to octahedral, but distorted on account of the limited bite angles of the polypyridyl ligands. The complexes are linked by O—H⋯O hydro...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254339/ https://www.ncbi.nlm.nih.gov/pubmed/22259372 http://dx.doi.org/10.1107/S1600536811054195 |
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author | Nielsen, Anne McKenzie, Christine J. Bond, Andrew D. |
author_facet | Nielsen, Anne McKenzie, Christine J. Bond, Andrew D. |
author_sort | Nielsen, Anne |
collection | PubMed |
description | In the title compound, [RuCl(C(15)H(11)N(3))(C(12)H(8)N(2)O(4))]ClO(4)·C(2)H(5)OH·H(2)O, the geometry of the ClN(5) coordination set around the Ru(II) atom is close to octahedral, but distorted on account of the limited bite angles of the polypyridyl ligands. The complexes are linked by O—H⋯O hydrogen bonds between the carboxyl groups and the crystal lattice water molecules into chains along [110]. Face-to-face stacking interactions are formed between terpyridine ligands, with interplanar separations of 3.66 (1) and 3.42 (1) Å, and between bipyridine-4,4′-dicarboxylic acid ligands, with interplanar separations of 3.65 (1) and 3.72 (1) Å. Three O atoms of the perchlorate ion are each disordered equally over two positions. The hydroxy group of the ethanol molecule is also disordered over two sites with refined occupancies of 0.794 (9) and 0.206 (9). |
format | Online Article Text |
id | pubmed-3254339 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543392012-01-18 (2,2′-Bipyridine-4,4′-dicarboxylic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate Nielsen, Anne McKenzie, Christine J. Bond, Andrew D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(C(15)H(11)N(3))(C(12)H(8)N(2)O(4))]ClO(4)·C(2)H(5)OH·H(2)O, the geometry of the ClN(5) coordination set around the Ru(II) atom is close to octahedral, but distorted on account of the limited bite angles of the polypyridyl ligands. The complexes are linked by O—H⋯O hydrogen bonds between the carboxyl groups and the crystal lattice water molecules into chains along [110]. Face-to-face stacking interactions are formed between terpyridine ligands, with interplanar separations of 3.66 (1) and 3.42 (1) Å, and between bipyridine-4,4′-dicarboxylic acid ligands, with interplanar separations of 3.65 (1) and 3.72 (1) Å. Three O atoms of the perchlorate ion are each disordered equally over two positions. The hydroxy group of the ethanol molecule is also disordered over two sites with refined occupancies of 0.794 (9) and 0.206 (9). International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254339/ /pubmed/22259372 http://dx.doi.org/10.1107/S1600536811054195 Text en © Nielsen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Nielsen, Anne McKenzie, Christine J. Bond, Andrew D. (2,2′-Bipyridine-4,4′-dicarboxylic acid-κ(2) N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3) N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate |
title | (2,2′-Bipyridine-4,4′-dicarboxylic acid-κ(2)
N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3)
N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate |
title_full | (2,2′-Bipyridine-4,4′-dicarboxylic acid-κ(2)
N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3)
N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate |
title_fullStr | (2,2′-Bipyridine-4,4′-dicarboxylic acid-κ(2)
N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3)
N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate |
title_full_unstemmed | (2,2′-Bipyridine-4,4′-dicarboxylic acid-κ(2)
N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3)
N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate |
title_short | (2,2′-Bipyridine-4,4′-dicarboxylic acid-κ(2)
N,N′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3)
N,N′,N′′)ruthenium(II) perchlorate ethanol monosolvate monohydrate |
title_sort | (2,2′-bipyridine-4,4′-dicarboxylic acid-κ(2)
n,n′)chlorido(2,2′:6′,2′′-terpyridyl-κ(3)
n,n′,n′′)ruthenium(ii) perchlorate ethanol monosolvate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254339/ https://www.ncbi.nlm.nih.gov/pubmed/22259372 http://dx.doi.org/10.1107/S1600536811054195 |
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