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Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV)

The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetra­hedrally coordinated Sn(IV) atom; the dithio­carbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and...

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Detalles Bibliográficos
Autores principales: Kamaludin, Nurul Farahana, Baba, Ibrahim, Awang, Normah, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254340/
https://www.ncbi.nlm.nih.gov/pubmed/22259373
http://dx.doi.org/10.1107/S160053681105392X
Descripción
Sumario:The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetra­hedrally coordinated Sn(IV) atom; the dithio­carbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H⋯S inter­actions lead to the formation of a linear supra­molecular chain along the b axis. The chains are aligned into layers by C—H⋯π inter­actions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites.