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Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV)
The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetrahedrally coordinated Sn(IV) atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254340/ https://www.ncbi.nlm.nih.gov/pubmed/22259373 http://dx.doi.org/10.1107/S160053681105392X |
Sumario: | The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetrahedrally coordinated Sn(IV) atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H⋯S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C—H⋯π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites. |
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