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Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV)

The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetra­hedrally coordinated Sn(IV) atom; the dithio­carbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and...

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Autores principales: Kamaludin, Nurul Farahana, Baba, Ibrahim, Awang, Normah, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254340/
https://www.ncbi.nlm.nih.gov/pubmed/22259373
http://dx.doi.org/10.1107/S160053681105392X
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author Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_facet Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Kamaludin, Nurul Farahana
collection PubMed
description The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetra­hedrally coordinated Sn(IV) atom; the dithio­carbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H⋯S inter­actions lead to the formation of a linear supra­molecular chain along the b axis. The chains are aligned into layers by C—H⋯π inter­actions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites.
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spelling pubmed-32543402012-01-18 Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV) Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetra­hedrally coordinated Sn(IV) atom; the dithio­carbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H⋯S inter­actions lead to the formation of a linear supra­molecular chain along the b axis. The chains are aligned into layers by C—H⋯π inter­actions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254340/ /pubmed/22259373 http://dx.doi.org/10.1107/S160053681105392X Text en © Kamaludin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV)
title Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV)
title_full Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV)
title_fullStr Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV)
title_full_unstemmed Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV)
title_short Di-n-butyl­bis­(N-ethyl-N-phenyl­dithio­carbamato-κS)tin(IV)
title_sort di-n-butyl­bis­(n-ethyl-n-phenyl­dithio­carbamato-κs)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254340/
https://www.ncbi.nlm.nih.gov/pubmed/22259373
http://dx.doi.org/10.1107/S160053681105392X
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