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Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV)
The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetrahedrally coordinated Sn(IV) atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254340/ https://www.ncbi.nlm.nih.gov/pubmed/22259373 http://dx.doi.org/10.1107/S160053681105392X |
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author | Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
author_facet | Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
author_sort | Kamaludin, Nurul Farahana |
collection | PubMed |
description | The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetrahedrally coordinated Sn(IV) atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H⋯S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C—H⋯π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites. |
format | Online Article Text |
id | pubmed-3254340 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543402012-01-18 Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV) Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(4)H(9))(2)(C(9)H(10)NS(2))(2)], features a tetrahedrally coordinated Sn(IV) atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the Sn(IV) atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H⋯S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C—H⋯π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254340/ /pubmed/22259373 http://dx.doi.org/10.1107/S160053681105392X Text en © Kamaludin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV) |
title | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV) |
title_full | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV) |
title_fullStr | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV) |
title_full_unstemmed | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV) |
title_short | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato-κS)tin(IV) |
title_sort | di-n-butylbis(n-ethyl-n-phenyldithiocarbamato-κs)tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254340/ https://www.ncbi.nlm.nih.gov/pubmed/22259373 http://dx.doi.org/10.1107/S160053681105392X |
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