Cargando…
Bis[μ-N-(diethylamino-κN)dimethylsilylanilido-κ(2) N:N]bis[chloridocobalt(II)]
In the title binuclear Co(II) complex, [Co(2)(C(12)H(21)N(2)Si)(2)Cl(2)], an inversion center is located at the mid-point between the two Co atoms in the dimeric molecule. The bidentate N-silylated anilide ligand coordinates the Co(II) atom in an N,N′-chelating mode and provides the anilide N atom...
Autor principal: | |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254341/ https://www.ncbi.nlm.nih.gov/pubmed/22259375 http://dx.doi.org/10.1107/S1600536811054602 |
Sumario: | In the title binuclear Co(II) complex, [Co(2)(C(12)H(21)N(2)Si)(2)Cl(2)], an inversion center is located at the mid-point between the two Co atoms in the dimeric molecule. The bidentate N-silylated anilide ligand coordinates the Co(II) atom in an N,N′-chelating mode and provides the anilide N atom as a bridge to link two Co(II) atoms. The two ends of the N—Si—N chelating unit exhibit different affinities for the metal atom. The Co—N(anilide) bond is 2.031 (6) Å and Co—N(amino) bond is 2.214 (6) Å. The four-coordinate Co atom presents a distorted tetrahedral geometry, while the dimeric aggregation exhibits a (CoN)(2) rhombus core with 1.998 (6) Å as the shortest sides and shows a ladder structure composed of Co, N and Si atoms. |
---|