Cargando…

{4,4′-Dimethyl-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}nickel(II) monohydrate

In the title compound, [Ni(C(21)H(24)N(2)O(2))]·H(2)O, both the complex mol­ecule and the water mol­ecule lie on a twofold rotation axis. The Ni(II) ion is coordinated in a distorted square-planar geometry by the tetra­dentate ligand. The dihedral angle between the two symmetry-related benzene rings...

Descripción completa

Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Sharafi, Zahra, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254342/
https://www.ncbi.nlm.nih.gov/pubmed/22259376
http://dx.doi.org/10.1107/S1600536811054262
Descripción
Sumario:In the title compound, [Ni(C(21)H(24)N(2)O(2))]·H(2)O, both the complex mol­ecule and the water mol­ecule lie on a twofold rotation axis. The Ni(II) ion is coordinated in a distorted square-planar geometry by the tetra­dentate ligand. The dihedral angle between the two symmetry-related benzene rings is 47.12 (8)°. In the crystal, pairs of symmetry-related O—H⋯O hydrogen bonds form R (2) (2)(6) ring motifs. In addition, there are weak inter­molecular C—H⋯O hydrogen bonds, and π–π stacking inter­actions with a centroid–centroid distance of 3.4760 (8) Å.