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Bis(4-fluorobenzyl)bis(4-phenyl-5-sulfanylidene-4,5-dihydro-1,3,4-thiodiazole-2-thiolato)tin(IV)
In the title complex, [Sn(C(7)H(6)F)(2)(C(8)H(5)N(2)S(3))(2)], including the weak Sn—N interactions, the Sn(IV) atom is situated in a distorted trans-octahedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanylidene-4,5-dihydro-1,3,4-thiodiazole-2-thiolate ligan...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254343/ https://www.ncbi.nlm.nih.gov/pubmed/22259377 http://dx.doi.org/10.1107/S1600536811054274 |
Sumario: | In the title complex, [Sn(C(7)H(6)F)(2)(C(8)H(5)N(2)S(3))(2)], including the weak Sn—N interactions, the Sn(IV) atom is situated in a distorted trans-octahedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanylidene-4,5-dihydro-1,3,4-thiodiazole-2-thiolate ligands. The apical positions are occupied by two C atoms of 4-fluorobenzyl groups. |
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