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Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV)

In the title complex, [Sn(C(7)H(6)F)(2)(C(8)H(5)N(2)S(3))(2)], including the weak Sn—N inter­actions, the Sn(IV) atom is situated in a distorted trans-octa­hedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ate ligan...

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Detalles Bibliográficos
Autores principales: Li, Lei, Zeng, Suyuan, Yan, Nana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254343/
https://www.ncbi.nlm.nih.gov/pubmed/22259377
http://dx.doi.org/10.1107/S1600536811054274
Descripción
Sumario:In the title complex, [Sn(C(7)H(6)F)(2)(C(8)H(5)N(2)S(3))(2)], including the weak Sn—N inter­actions, the Sn(IV) atom is situated in a distorted trans-octa­hedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ate ligands. The apical positions are occupied by two C atoms of 4-fluoro­benzyl groups.