Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV)

In the title complex, [Sn(C(7)H(6)F)(2)(C(8)H(5)N(2)S(3))(2)], including the weak Sn—N inter­actions, the Sn(IV) atom is situated in a distorted trans-octa­hedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ate ligan...

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Detalles Bibliográficos
Autores principales: Li, Lei, Zeng, Suyuan, Yan, Nana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254343/
https://www.ncbi.nlm.nih.gov/pubmed/22259377
http://dx.doi.org/10.1107/S1600536811054274
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author Li, Lei
Zeng, Suyuan
Yan, Nana
author_facet Li, Lei
Zeng, Suyuan
Yan, Nana
author_sort Li, Lei
collection PubMed
description In the title complex, [Sn(C(7)H(6)F)(2)(C(8)H(5)N(2)S(3))(2)], including the weak Sn—N inter­actions, the Sn(IV) atom is situated in a distorted trans-octa­hedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ate ligands. The apical positions are occupied by two C atoms of 4-fluoro­benzyl groups.
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spelling pubmed-32543432012-01-18 Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV) Li, Lei Zeng, Suyuan Yan, Nana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Sn(C(7)H(6)F)(2)(C(8)H(5)N(2)S(3))(2)], including the weak Sn—N inter­actions, the Sn(IV) atom is situated in a distorted trans-octa­hedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ate ligands. The apical positions are occupied by two C atoms of 4-fluoro­benzyl groups. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254343/ /pubmed/22259377 http://dx.doi.org/10.1107/S1600536811054274 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Lei
Zeng, Suyuan
Yan, Nana
Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV)
title Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV)
title_full Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV)
title_fullStr Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV)
title_full_unstemmed Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV)
title_short Bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(IV)
title_sort bis(4-fluoro­benz­yl)bis­(4-phenyl-5-sulfanyl­idene-4,5-dihydro-1,3,4-thio­diazole-2-thiol­ato)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254343/
https://www.ncbi.nlm.nih.gov/pubmed/22259377
http://dx.doi.org/10.1107/S1600536811054274
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AT zengsuyuan bis4fluorobenzylbis4phenyl5sulfanylidene45dihydro134thiodiazole2thiolatotiniv
AT yannana bis4fluorobenzylbis4phenyl5sulfanylidene45dihydro134thiodiazole2thiolatotiniv

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