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Poly[(2,2′-bipyridine-κ(2) N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5) O (1),O (1′):O (1):O (3),O (3′))cadmium]
In the crystal structure of the polymeric title complex, [Cd(C(11)H(10)O(4))(C(10)H(8)N(2))](n), the Cd(II) cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254344/ https://www.ncbi.nlm.nih.gov/pubmed/22259378 http://dx.doi.org/10.1107/S1600536811054183 |
Sumario: | In the crystal structure of the polymeric title complex, [Cd(C(11)H(10)O(4))(C(10)H(8)N(2))](n), the Cd(II) cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal–bipyramidal geometry. Each TMIPA anion bridges three Cd(II) cations, forming polymeric complex sheets parallel to (001). Weak C—H⋯O hydrogen bonding occurs between adjacent sheets. |
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