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Poly[(2,2′-bipyridine-κ(2) N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5) O (1),O (1′):O (1):O (3),O (3′))cadmium]
In the crystal structure of the polymeric title complex, [Cd(C(11)H(10)O(4))(C(10)H(8)N(2))](n), the Cd(II) cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254344/ https://www.ncbi.nlm.nih.gov/pubmed/22259378 http://dx.doi.org/10.1107/S1600536811054183 |
| _version_ | 1782220838189137920 |
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| author | Hou, Shao-Gang Jin, Mei-Fang |
| author_facet | Hou, Shao-Gang Jin, Mei-Fang |
| author_sort | Hou, Shao-Gang |
| collection | PubMed |
| description | In the crystal structure of the polymeric title complex, [Cd(C(11)H(10)O(4))(C(10)H(8)N(2))](n), the Cd(II) cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal–bipyramidal geometry. Each TMIPA anion bridges three Cd(II) cations, forming polymeric complex sheets parallel to (001). Weak C—H⋯O hydrogen bonding occurs between adjacent sheets. |
| format | Online Article Text |
| id | pubmed-3254344 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32543442012-01-18 Poly[(2,2′-bipyridine-κ(2) N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5) O (1),O (1′):O (1):O (3),O (3′))cadmium] Hou, Shao-Gang Jin, Mei-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the polymeric title complex, [Cd(C(11)H(10)O(4))(C(10)H(8)N(2))](n), the Cd(II) cation is chelated by one 2,2-bipyridine ligand and two carboxyl groups from two trimethylisophthalate (TMIPA) anions, and is further coordinated by one carboxylate O atom from a third TMIPA anion, forming a distorted pentagonal–bipyramidal geometry. Each TMIPA anion bridges three Cd(II) cations, forming polymeric complex sheets parallel to (001). Weak C—H⋯O hydrogen bonding occurs between adjacent sheets. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254344/ /pubmed/22259378 http://dx.doi.org/10.1107/S1600536811054183 Text en © Hou and Jin 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hou, Shao-Gang Jin, Mei-Fang Poly[(2,2′-bipyridine-κ(2) N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5) O (1),O (1′):O (1):O (3),O (3′))cadmium] |
| title | Poly[(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5)
O
(1),O
(1′):O
(1):O
(3),O
(3′))cadmium] |
| title_full | Poly[(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5)
O
(1),O
(1′):O
(1):O
(3),O
(3′))cadmium] |
| title_fullStr | Poly[(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5)
O
(1),O
(1′):O
(1):O
(3),O
(3′))cadmium] |
| title_full_unstemmed | Poly[(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5)
O
(1),O
(1′):O
(1):O
(3),O
(3′))cadmium] |
| title_short | Poly[(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-2,4,6-trimethylisophthalato-κ(5)
O
(1),O
(1′):O
(1):O
(3),O
(3′))cadmium] |
| title_sort | poly[(2,2′-bipyridine-κ(2)
n,n′)(μ(3)-2,4,6-trimethylisophthalato-κ(5)
o
(1),o
(1′):o
(1):o
(3),o
(3′))cadmium] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254344/ https://www.ncbi.nlm.nih.gov/pubmed/22259378 http://dx.doi.org/10.1107/S1600536811054183 |
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