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{N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate
The title mononuclear complex, [Cu(C(18)H(12)N(2)O(2))(C(12)H(8)N(2))]·CH(3)OH, contains one N′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidate ligand (L (2−)), a Cu(2+) cation, one 1,10-phenanthroline ligand and a methanol solvent molecule. The Cu(II) ion adopts a CuO(2)N(3) distorted squar...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254345/ https://www.ncbi.nlm.nih.gov/pubmed/22259379 http://dx.doi.org/10.1107/S1600536811054316 |
| _version_ | 1782220838418776064 |
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| author | Liu, Bao-Lin Dong, De-Ming Hua, Xiu-Yi Zhu, Jian-Wei |
| author_facet | Liu, Bao-Lin Dong, De-Ming Hua, Xiu-Yi Zhu, Jian-Wei |
| author_sort | Liu, Bao-Lin |
| collection | PubMed |
| description | The title mononuclear complex, [Cu(C(18)H(12)N(2)O(2))(C(12)H(8)N(2))]·CH(3)OH, contains one N′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidate ligand (L (2−)), a Cu(2+) cation, one 1,10-phenanthroline ligand and a methanol solvent molecule. The Cu(II) ion adopts a CuO(2)N(3) distorted square-pyramidal coordination. An O—H⋯O hydrogen bond is formed between the methanol solvent molecule and the hydrazide O atom of the L (2−) ligand. |
| format | Online Article Text |
| id | pubmed-3254345 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32543452012-01-18 {N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate Liu, Bao-Lin Dong, De-Ming Hua, Xiu-Yi Zhu, Jian-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear complex, [Cu(C(18)H(12)N(2)O(2))(C(12)H(8)N(2))]·CH(3)OH, contains one N′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidate ligand (L (2−)), a Cu(2+) cation, one 1,10-phenanthroline ligand and a methanol solvent molecule. The Cu(II) ion adopts a CuO(2)N(3) distorted square-pyramidal coordination. An O—H⋯O hydrogen bond is formed between the methanol solvent molecule and the hydrazide O atom of the L (2−) ligand. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254345/ /pubmed/22259379 http://dx.doi.org/10.1107/S1600536811054316 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Bao-Lin Dong, De-Ming Hua, Xiu-Yi Zhu, Jian-Wei {N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate |
| title | {N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate |
| title_full | {N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate |
| title_fullStr | {N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate |
| title_full_unstemmed | {N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate |
| title_short | {N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate |
| title_sort | {n′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(ii) methanol monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254345/ https://www.ncbi.nlm.nih.gov/pubmed/22259379 http://dx.doi.org/10.1107/S1600536811054316 |
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