Bis(μ-trimethyl­silanolato-κ(2) O:O)bis­{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) N,O]zinc}

The binuclear title complex, [Zn(2)(C(22)H(28)N(3)O)(2)(C(3)H(9)OSi)(2)], has a crystallographic imposed centre of symmetry. The Zn(II) atom is coordinated by three O and one N atom from one 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolate ligand and two bridging trimethyl­silanolate anions in...

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Detalles Bibliográficos
Autores principales: Lee, Hwi Hyun, Go, Min Jeong, Park, Ka Hyun, Kim, Youngjo, Lee, Junseong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254346/
https://www.ncbi.nlm.nih.gov/pubmed/22259380
http://dx.doi.org/10.1107/S1600536811054134
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author Lee, Hwi Hyun
Go, Min Jeong
Park, Ka Hyun
Kim, Youngjo
Lee, Junseong
author_facet Lee, Hwi Hyun
Go, Min Jeong
Park, Ka Hyun
Kim, Youngjo
Lee, Junseong
author_sort Lee, Hwi Hyun
collection PubMed
description The binuclear title complex, [Zn(2)(C(22)H(28)N(3)O)(2)(C(3)H(9)OSi)(2)], has a crystallographic imposed centre of symmetry. The Zn(II) atom is coordinated by three O and one N atom from one 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolate ligand and two bridging trimethyl­silanolate anions in a distorted tetra­hedral geometry. The dihedral angle between the benzotriazole ring system and the benzene ring is 19.83 (5)°. The tert-pentyl groups are disordered over two orientations with refined site-occupancy ratios of 0.858 (4):0.142 (4) and 0.665 (6):0.335 (6).
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spelling pubmed-32543462012-01-18 Bis(μ-trimethyl­silanolato-κ(2) O:O)bis­{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) N,O]zinc} Lee, Hwi Hyun Go, Min Jeong Park, Ka Hyun Kim, Youngjo Lee, Junseong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear title complex, [Zn(2)(C(22)H(28)N(3)O)(2)(C(3)H(9)OSi)(2)], has a crystallographic imposed centre of symmetry. The Zn(II) atom is coordinated by three O and one N atom from one 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolate ligand and two bridging trimethyl­silanolate anions in a distorted tetra­hedral geometry. The dihedral angle between the benzotriazole ring system and the benzene ring is 19.83 (5)°. The tert-pentyl groups are disordered over two orientations with refined site-occupancy ratios of 0.858 (4):0.142 (4) and 0.665 (6):0.335 (6). International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254346/ /pubmed/22259380 http://dx.doi.org/10.1107/S1600536811054134 Text en © Lee et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, Hwi Hyun
Go, Min Jeong
Park, Ka Hyun
Kim, Youngjo
Lee, Junseong
Bis(μ-trimethyl­silanolato-κ(2) O:O)bis­{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) N,O]zinc}
title Bis(μ-trimethyl­silanolato-κ(2) O:O)bis­{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) N,O]zinc}
title_full Bis(μ-trimethyl­silanolato-κ(2) O:O)bis­{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) N,O]zinc}
title_fullStr Bis(μ-trimethyl­silanolato-κ(2) O:O)bis­{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) N,O]zinc}
title_full_unstemmed Bis(μ-trimethyl­silanolato-κ(2) O:O)bis­{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) N,O]zinc}
title_short Bis(μ-trimethyl­silanolato-κ(2) O:O)bis­{[2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) N,O]zinc}
title_sort bis(μ-trimethyl­silanolato-κ(2) o:o)bis­{[2-(2h-benzotriazol-2-yl)-4,6-di-tert-pentyl­phenolato-κ(2) n,o]zinc}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254346/
https://www.ncbi.nlm.nih.gov/pubmed/22259380
http://dx.doi.org/10.1107/S1600536811054134
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