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Bis(μ-pyridinium-2-carboxylato-κ(2) O:O′)bis[triaqua(sulfato-κO)manganese(II)]
The asymmetric unit of the title compound, [Mn(2)(SO(4))(2)(C(6)H(5)NO(2))(2)(H(2)O)(6)], comprises half of a centrosymmetric dimer. The Mn(II) atom is coordinated by two O atoms of the monodentate carboxylate ligand, an O atom of the sulfate anion in axial position and three water molecules in a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254347/ https://www.ncbi.nlm.nih.gov/pubmed/22259381 http://dx.doi.org/10.1107/S1600536811054596 |
Sumario: | The asymmetric unit of the title compound, [Mn(2)(SO(4))(2)(C(6)H(5)NO(2))(2)(H(2)O)(6)], comprises half of a centrosymmetric dimer. The Mn(II) atom is coordinated by two O atoms of the monodentate carboxylate ligand, an O atom of the sulfate anion in axial position and three water molecules in a distorted octahedral geometry. In the crystal, molecules are connected through N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.842 (2) Å]. |
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