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Bis(μ-pyridinium-2-carboxylato-κ(2) O:O′)bis[triaqua(sulfato-κO)manganese(II)]
The asymmetric unit of the title compound, [Mn(2)(SO(4))(2)(C(6)H(5)NO(2))(2)(H(2)O)(6)], comprises half of a centrosymmetric dimer. The Mn(II) atom is coordinated by two O atoms of the monodentate carboxylate ligand, an O atom of the sulfate anion in axial position and three water molecules in a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254347/ https://www.ncbi.nlm.nih.gov/pubmed/22259381 http://dx.doi.org/10.1107/S1600536811054596 |
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author | Rasekh, Hossein Ali Bahrami, Bohlul |
author_facet | Rasekh, Hossein Ali Bahrami, Bohlul |
author_sort | Rasekh, Hossein Ali |
collection | PubMed |
description | The asymmetric unit of the title compound, [Mn(2)(SO(4))(2)(C(6)H(5)NO(2))(2)(H(2)O)(6)], comprises half of a centrosymmetric dimer. The Mn(II) atom is coordinated by two O atoms of the monodentate carboxylate ligand, an O atom of the sulfate anion in axial position and three water molecules in a distorted octahedral geometry. In the crystal, molecules are connected through N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.842 (2) Å]. |
format | Online Article Text |
id | pubmed-3254347 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543472012-01-18 Bis(μ-pyridinium-2-carboxylato-κ(2) O:O′)bis[triaqua(sulfato-κO)manganese(II)] Rasekh, Hossein Ali Bahrami, Bohlul Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(2)(SO(4))(2)(C(6)H(5)NO(2))(2)(H(2)O)(6)], comprises half of a centrosymmetric dimer. The Mn(II) atom is coordinated by two O atoms of the monodentate carboxylate ligand, an O atom of the sulfate anion in axial position and three water molecules in a distorted octahedral geometry. In the crystal, molecules are connected through N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.842 (2) Å]. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254347/ /pubmed/22259381 http://dx.doi.org/10.1107/S1600536811054596 Text en © Rasekh and Bahrami 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rasekh, Hossein Ali Bahrami, Bohlul Bis(μ-pyridinium-2-carboxylato-κ(2) O:O′)bis[triaqua(sulfato-κO)manganese(II)] |
title | Bis(μ-pyridinium-2-carboxylato-κ(2)
O:O′)bis[triaqua(sulfato-κO)manganese(II)] |
title_full | Bis(μ-pyridinium-2-carboxylato-κ(2)
O:O′)bis[triaqua(sulfato-κO)manganese(II)] |
title_fullStr | Bis(μ-pyridinium-2-carboxylato-κ(2)
O:O′)bis[triaqua(sulfato-κO)manganese(II)] |
title_full_unstemmed | Bis(μ-pyridinium-2-carboxylato-κ(2)
O:O′)bis[triaqua(sulfato-κO)manganese(II)] |
title_short | Bis(μ-pyridinium-2-carboxylato-κ(2)
O:O′)bis[triaqua(sulfato-κO)manganese(II)] |
title_sort | bis(μ-pyridinium-2-carboxylato-κ(2)
o:o′)bis[triaqua(sulfato-κo)manganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254347/ https://www.ncbi.nlm.nih.gov/pubmed/22259381 http://dx.doi.org/10.1107/S1600536811054596 |
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