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Bis(μ-pyridinium-2-carboxyl­ato-κ(2) O:O′)bis­[triaqua­(sulfato-κO)manganese(II)]

The asymmetric unit of the title compound, [Mn(2)(SO(4))(2)(C(6)H(5)NO(2))(2)(H(2)O)(6)], comprises half of a centrosymmetric dimer. The Mn(II) atom is coordinated by two O atoms of the monodentate carboxyl­ate ligand, an O atom of the sulfate anion in axial position and three water mol­ecules in a...

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Detalles Bibliográficos
Autores principales: Rasekh, Hossein Ali, Bahrami, Bohlul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254347/
https://www.ncbi.nlm.nih.gov/pubmed/22259381
http://dx.doi.org/10.1107/S1600536811054596
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author Rasekh, Hossein Ali
Bahrami, Bohlul
author_facet Rasekh, Hossein Ali
Bahrami, Bohlul
author_sort Rasekh, Hossein Ali
collection PubMed
description The asymmetric unit of the title compound, [Mn(2)(SO(4))(2)(C(6)H(5)NO(2))(2)(H(2)O)(6)], comprises half of a centrosymmetric dimer. The Mn(II) atom is coordinated by two O atoms of the monodentate carboxyl­ate ligand, an O atom of the sulfate anion in axial position and three water mol­ecules in a distorted octa­hedral geometry. In the crystal, mol­ecules are connected through N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.842 (2) Å].
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spelling pubmed-32543472012-01-18 Bis(μ-pyridinium-2-carboxyl­ato-κ(2) O:O′)bis­[triaqua­(sulfato-κO)manganese(II)] Rasekh, Hossein Ali Bahrami, Bohlul Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(2)(SO(4))(2)(C(6)H(5)NO(2))(2)(H(2)O)(6)], comprises half of a centrosymmetric dimer. The Mn(II) atom is coordinated by two O atoms of the monodentate carboxyl­ate ligand, an O atom of the sulfate anion in axial position and three water mol­ecules in a distorted octa­hedral geometry. In the crystal, mol­ecules are connected through N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network. The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.842 (2) Å]. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254347/ /pubmed/22259381 http://dx.doi.org/10.1107/S1600536811054596 Text en © Rasekh and Bahrami 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rasekh, Hossein Ali
Bahrami, Bohlul
Bis(μ-pyridinium-2-carboxyl­ato-κ(2) O:O′)bis­[triaqua­(sulfato-κO)manganese(II)]
title Bis(μ-pyridinium-2-carboxyl­ato-κ(2) O:O′)bis­[triaqua­(sulfato-κO)manganese(II)]
title_full Bis(μ-pyridinium-2-carboxyl­ato-κ(2) O:O′)bis­[triaqua­(sulfato-κO)manganese(II)]
title_fullStr Bis(μ-pyridinium-2-carboxyl­ato-κ(2) O:O′)bis­[triaqua­(sulfato-κO)manganese(II)]
title_full_unstemmed Bis(μ-pyridinium-2-carboxyl­ato-κ(2) O:O′)bis­[triaqua­(sulfato-κO)manganese(II)]
title_short Bis(μ-pyridinium-2-carboxyl­ato-κ(2) O:O′)bis­[triaqua­(sulfato-κO)manganese(II)]
title_sort bis(μ-pyridinium-2-carboxyl­ato-κ(2) o:o′)bis­[triaqua­(sulfato-κo)manganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254347/
https://www.ncbi.nlm.nih.gov/pubmed/22259381
http://dx.doi.org/10.1107/S1600536811054596
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