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cis-Bis(4-methylpiperazine-1-carbodithioato-κ(2) S,S′)bis(pyridine-κN)cadmium
In the title complex, [Cd(C(6)H(11)N(2)S(2))(2)(C(5)H(5)N)(2)], the Cd(II) ion is hexacoordinated by two N atoms from two pyridine ligands and by four S atoms from two dithiocarbamate ligands in a distorted octahedral geometry. The Cd(II) ion lies on a twofold axis. The piperazine ring is in chai...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254348/ https://www.ncbi.nlm.nih.gov/pubmed/22259382 http://dx.doi.org/10.1107/S1600536811054791 |
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author | Valarmathi, P. Thirumaran, S. Kapoor, Kamini Gupta, Vivek K. Kant, Rajni |
author_facet | Valarmathi, P. Thirumaran, S. Kapoor, Kamini Gupta, Vivek K. Kant, Rajni |
author_sort | Valarmathi, P. |
collection | PubMed |
description | In the title complex, [Cd(C(6)H(11)N(2)S(2))(2)(C(5)H(5)N)(2)], the Cd(II) ion is hexacoordinated by two N atoms from two pyridine ligands and by four S atoms from two dithiocarbamate ligands in a distorted octahedral geometry. The Cd(II) ion lies on a twofold axis. The piperazine ring is in chair conformation and its least-squares plane makes a dihedral angle of 81.4 (1)° with that of the pyridine ring. |
format | Online Article Text |
id | pubmed-3254348 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543482012-01-18 cis-Bis(4-methylpiperazine-1-carbodithioato-κ(2) S,S′)bis(pyridine-κN)cadmium Valarmathi, P. Thirumaran, S. Kapoor, Kamini Gupta, Vivek K. Kant, Rajni Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(6)H(11)N(2)S(2))(2)(C(5)H(5)N)(2)], the Cd(II) ion is hexacoordinated by two N atoms from two pyridine ligands and by four S atoms from two dithiocarbamate ligands in a distorted octahedral geometry. The Cd(II) ion lies on a twofold axis. The piperazine ring is in chair conformation and its least-squares plane makes a dihedral angle of 81.4 (1)° with that of the pyridine ring. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254348/ /pubmed/22259382 http://dx.doi.org/10.1107/S1600536811054791 Text en © Valarmathi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Valarmathi, P. Thirumaran, S. Kapoor, Kamini Gupta, Vivek K. Kant, Rajni cis-Bis(4-methylpiperazine-1-carbodithioato-κ(2) S,S′)bis(pyridine-κN)cadmium |
title |
cis-Bis(4-methylpiperazine-1-carbodithioato-κ(2)
S,S′)bis(pyridine-κN)cadmium |
title_full |
cis-Bis(4-methylpiperazine-1-carbodithioato-κ(2)
S,S′)bis(pyridine-κN)cadmium |
title_fullStr |
cis-Bis(4-methylpiperazine-1-carbodithioato-κ(2)
S,S′)bis(pyridine-κN)cadmium |
title_full_unstemmed |
cis-Bis(4-methylpiperazine-1-carbodithioato-κ(2)
S,S′)bis(pyridine-κN)cadmium |
title_short |
cis-Bis(4-methylpiperazine-1-carbodithioato-κ(2)
S,S′)bis(pyridine-κN)cadmium |
title_sort | cis-bis(4-methylpiperazine-1-carbodithioato-κ(2)
s,s′)bis(pyridine-κn)cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254348/ https://www.ncbi.nlm.nih.gov/pubmed/22259382 http://dx.doi.org/10.1107/S1600536811054791 |
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