cis-Bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) S,S′)bis­(pyridine-κN)cadmium

In the title complex, [Cd(C(6)H(11)N(2)S(2))(2)(C(5)H(5)N)(2)], the Cd(II) ion is hexa­coordinated by two N atoms from two pyridine ligands and by four S atoms from two dithio­carbamate ligands in a distorted octa­hedral geometry. The Cd(II) ion lies on a twofold axis. The piperazine ring is in chai...

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Autores principales: Valarmathi, P., Thirumaran, S., Kapoor, Kamini, Gupta, Vivek K., Kant, Rajni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254348/
https://www.ncbi.nlm.nih.gov/pubmed/22259382
http://dx.doi.org/10.1107/S1600536811054791
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author Valarmathi, P.
Thirumaran, S.
Kapoor, Kamini
Gupta, Vivek K.
Kant, Rajni
author_facet Valarmathi, P.
Thirumaran, S.
Kapoor, Kamini
Gupta, Vivek K.
Kant, Rajni
author_sort Valarmathi, P.
collection PubMed
description In the title complex, [Cd(C(6)H(11)N(2)S(2))(2)(C(5)H(5)N)(2)], the Cd(II) ion is hexa­coordinated by two N atoms from two pyridine ligands and by four S atoms from two dithio­carbamate ligands in a distorted octa­hedral geometry. The Cd(II) ion lies on a twofold axis. The piperazine ring is in chair conformation and its least-squares plane makes a dihedral angle of 81.4 (1)° with that of the pyridine ring.
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spelling pubmed-32543482012-01-18 cis-Bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) S,S′)bis­(pyridine-κN)cadmium Valarmathi, P. Thirumaran, S. Kapoor, Kamini Gupta, Vivek K. Kant, Rajni Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(6)H(11)N(2)S(2))(2)(C(5)H(5)N)(2)], the Cd(II) ion is hexa­coordinated by two N atoms from two pyridine ligands and by four S atoms from two dithio­carbamate ligands in a distorted octa­hedral geometry. The Cd(II) ion lies on a twofold axis. The piperazine ring is in chair conformation and its least-squares plane makes a dihedral angle of 81.4 (1)° with that of the pyridine ring. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254348/ /pubmed/22259382 http://dx.doi.org/10.1107/S1600536811054791 Text en © Valarmathi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Valarmathi, P.
Thirumaran, S.
Kapoor, Kamini
Gupta, Vivek K.
Kant, Rajni
cis-Bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) S,S′)bis­(pyridine-κN)cadmium
title cis-Bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) S,S′)bis­(pyridine-κN)cadmium
title_full cis-Bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) S,S′)bis­(pyridine-κN)cadmium
title_fullStr cis-Bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) S,S′)bis­(pyridine-κN)cadmium
title_full_unstemmed cis-Bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) S,S′)bis­(pyridine-κN)cadmium
title_short cis-Bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) S,S′)bis­(pyridine-κN)cadmium
title_sort cis-bis(4-methyl­piperazine-1-carbo­dithio­ato-κ(2) s,s′)bis­(pyridine-κn)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254348/
https://www.ncbi.nlm.nih.gov/pubmed/22259382
http://dx.doi.org/10.1107/S1600536811054791
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