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2,2′,5,5′-Tetra­chloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide

In the title compound, C(24)H(24)Cl(4)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 58.09 (10) and 62.59 (10)°. The dihedral angle between the pendant rings is 81.64 (9)°. Both sulfonamide groups lie to the same side of the central ring but the C—S—N—C...

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Autores principales: Ejaz, Khan, Islam Ullah, Sheikh, Tahir Ali, Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254356/
https://www.ncbi.nlm.nih.gov/pubmed/22259436
http://dx.doi.org/10.1107/S1600536811045326
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author Ejaz,
Khan, Islam Ullah
Sheikh, Tahir Ali
Harrison, William T. A.
author_facet Ejaz,
Khan, Islam Ullah
Sheikh, Tahir Ali
Harrison, William T. A.
author_sort Ejaz,
collection PubMed
description In the title compound, C(24)H(24)Cl(4)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 58.09 (10) and 62.59 (10)°. The dihedral angle between the pendant rings is 81.64 (9)°. Both sulfonamide groups lie to the same side of the central ring but the C—S—N—C torsion angles [73.09 (16) and −117.35 (14)] and S—N—C—C torsion angles [−143.80 (14) and −111.45 (16)°] differ significantly for the two pendant chains. The N atoms are close to planar (bond angle sums = 356.4 and 359.5°). In the crystal, weak C—H⋯O and C—H⋯Cl inter­actions link the mol­ecules.
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spelling pubmed-32543562012-01-18 2,2′,5,5′-Tetra­chloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide Ejaz, Khan, Islam Ullah Sheikh, Tahir Ali Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(24)Cl(4)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 58.09 (10) and 62.59 (10)°. The dihedral angle between the pendant rings is 81.64 (9)°. Both sulfonamide groups lie to the same side of the central ring but the C—S—N—C torsion angles [73.09 (16) and −117.35 (14)] and S—N—C—C torsion angles [−143.80 (14) and −111.45 (16)°] differ significantly for the two pendant chains. The N atoms are close to planar (bond angle sums = 356.4 and 359.5°). In the crystal, weak C—H⋯O and C—H⋯Cl inter­actions link the mol­ecules. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254356/ /pubmed/22259436 http://dx.doi.org/10.1107/S1600536811045326 Text en © Ejaz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ejaz,
Khan, Islam Ullah
Sheikh, Tahir Ali
Harrison, William T. A.
2,2′,5,5′-Tetra­chloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide
title 2,2′,5,5′-Tetra­chloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide
title_full 2,2′,5,5′-Tetra­chloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide
title_fullStr 2,2′,5,5′-Tetra­chloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide
title_full_unstemmed 2,2′,5,5′-Tetra­chloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide
title_short 2,2′,5,5′-Tetra­chloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide
title_sort 2,2′,5,5′-tetra­chloro-n,n′-diethyl-n,n′-[benzene-1,3-diylbis(methyl­ene)]dibenzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254356/
https://www.ncbi.nlm.nih.gov/pubmed/22259436
http://dx.doi.org/10.1107/S1600536811045326
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