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2,2′,5,5′-Tetrachloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide
In the title compound, C(24)H(24)Cl(4)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 58.09 (10) and 62.59 (10)°. The dihedral angle between the pendant rings is 81.64 (9)°. Both sulfonamide groups lie to the same side of the central ring but the C—S—N—C...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254356/ https://www.ncbi.nlm.nih.gov/pubmed/22259436 http://dx.doi.org/10.1107/S1600536811045326 |
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author | Ejaz, Khan, Islam Ullah Sheikh, Tahir Ali Harrison, William T. A. |
author_facet | Ejaz, Khan, Islam Ullah Sheikh, Tahir Ali Harrison, William T. A. |
author_sort | Ejaz, |
collection | PubMed |
description | In the title compound, C(24)H(24)Cl(4)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 58.09 (10) and 62.59 (10)°. The dihedral angle between the pendant rings is 81.64 (9)°. Both sulfonamide groups lie to the same side of the central ring but the C—S—N—C torsion angles [73.09 (16) and −117.35 (14)] and S—N—C—C torsion angles [−143.80 (14) and −111.45 (16)°] differ significantly for the two pendant chains. The N atoms are close to planar (bond angle sums = 356.4 and 359.5°). In the crystal, weak C—H⋯O and C—H⋯Cl interactions link the molecules. |
format | Online Article Text |
id | pubmed-3254356 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543562012-01-18 2,2′,5,5′-Tetrachloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide Ejaz, Khan, Islam Ullah Sheikh, Tahir Ali Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(24)Cl(4)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 58.09 (10) and 62.59 (10)°. The dihedral angle between the pendant rings is 81.64 (9)°. Both sulfonamide groups lie to the same side of the central ring but the C—S—N—C torsion angles [73.09 (16) and −117.35 (14)] and S—N—C—C torsion angles [−143.80 (14) and −111.45 (16)°] differ significantly for the two pendant chains. The N atoms are close to planar (bond angle sums = 356.4 and 359.5°). In the crystal, weak C—H⋯O and C—H⋯Cl interactions link the molecules. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254356/ /pubmed/22259436 http://dx.doi.org/10.1107/S1600536811045326 Text en © Ejaz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ejaz, Khan, Islam Ullah Sheikh, Tahir Ali Harrison, William T. A. 2,2′,5,5′-Tetrachloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide |
title | 2,2′,5,5′-Tetrachloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide |
title_full | 2,2′,5,5′-Tetrachloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide |
title_fullStr | 2,2′,5,5′-Tetrachloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide |
title_full_unstemmed | 2,2′,5,5′-Tetrachloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide |
title_short | 2,2′,5,5′-Tetrachloro-N,N′-diethyl-N,N′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide |
title_sort | 2,2′,5,5′-tetrachloro-n,n′-diethyl-n,n′-[benzene-1,3-diylbis(methylene)]dibenzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254356/ https://www.ncbi.nlm.nih.gov/pubmed/22259436 http://dx.doi.org/10.1107/S1600536811045326 |
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