Cargando…

1-Hexyl-1,3,6,8-tetra­aza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide

In the title compound, C(13)H(27)N(4) (+)·I(−), the ethyl­ene bridge is distorted from the ideal D (2d) symmetry wherein an N—C—C—N planar bridge, around whose C—C bond the C—N and C—H bonds are exactly eclipsed, is disordered over two sites with equal occupancies. In both disorder components, the h...

Descripción completa

Detalles Bibliográficos
Autores principales: Rivera, Augusto, Sadat-Bernal, John, Ríos-Motta, Jaime, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254358/
https://www.ncbi.nlm.nih.gov/pubmed/22259454
http://dx.doi.org/10.1107/S1600536811050781
Descripción
Sumario:In the title compound, C(13)H(27)N(4) (+)·I(−), the ethyl­ene bridge is distorted from the ideal D (2d) symmetry wherein an N—C—C—N planar bridge, around whose C—C bond the C—N and C—H bonds are exactly eclipsed, is disordered over two sites with equal occupancies. In both disorder components, the hexyl chain adopts an ideal all-trans conformation. In the crystal, adjacent ions are connected by C—H⋯I hydrogen bonds, forming ionic pairs that are further linked into chains along [101] via a second C—H⋯I inter­action.