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1-Hexyl-1,3,6,8-tetraazatricyclo[4.3.1.1(3,8)]undecan-1-ium iodide
In the title compound, C(13)H(27)N(4) (+)·I(−), the ethylene bridge is distorted from the ideal D (2d) symmetry wherein an N—C—C—N planar bridge, around whose C—C bond the C—N and C—H bonds are exactly eclipsed, is disordered over two sites with equal occupancies. In both disorder components, the h...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254358/ https://www.ncbi.nlm.nih.gov/pubmed/22259454 http://dx.doi.org/10.1107/S1600536811050781 |
Sumario: | In the title compound, C(13)H(27)N(4) (+)·I(−), the ethylene bridge is distorted from the ideal D (2d) symmetry wherein an N—C—C—N planar bridge, around whose C—C bond the C—N and C—H bonds are exactly eclipsed, is disordered over two sites with equal occupancies. In both disorder components, the hexyl chain adopts an ideal all-trans conformation. In the crystal, adjacent ions are connected by C—H⋯I hydrogen bonds, forming ionic pairs that are further linked into chains along [101] via a second C—H⋯I interaction. |
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